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Rotational energies are quantized. For a diatomic molecule like CO or HCl, or a linear polyatomic molecule like OCS in its ground vibrational state, the allowed rotational energies in the rigid rotor approximation are = = (+) = (+). J is the quantum number for total rotational angular momentum and takes all integer values starting at zero, i.e., =,,, …, = is the rotational constant, and is ...
Every rotation in three dimensions is defined by its axis (a vector along this axis is unchanged by the rotation), and its angle — the amount of rotation about that axis (Euler rotation theorem). There are several methods to compute the axis and angle from a rotation matrix (see also axis–angle representation ).
Consider a body (for example a fixed volume of atmosphere) moving along at a given latitude at velocity in the Earth's rotating reference frame. In the local reference frame of the body, the vertical direction is parallel to the radial vector pointing from the center of the Earth to the location of the body and the horizontal direction is perpendicular to this vertical direction and in the ...
Rotational diffusion is the rotational movement which acts upon any object such as particles, molecules, atoms when present in a fluid, by random changes in their orientations. Although the directions and intensities of these changes are statistically random, they do not arise randomly and are instead the result of interactions between particles.
For example, the molecule methane is a spherical top but the asymmetric C-H stretching band shows rotational fine structure in the infrared spectrum, illustrated in rovibrational coupling. This spectrum is also interesting because it shows clear evidence of Coriolis coupling in the asymmetric structure of the band.
Radius of gyration (in polymer science)(, unit: nm or SI unit: m): For a macromolecule composed of mass elements, of masses , =1,2,…,, located at fixed distances from the centre of mass, the radius of gyration is the square-root of the mass average of over all mass elements, i.e.,
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Rotation about single bond of butane to interconvert one conformation to another. The gauche conformation on the right is a conformer, while the eclipsed conformation on the left is a transition state between conformers. Above: Newman projection; below: depiction of spatial orientation.