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It may be noted that, for polymers, the strain is commonly expressed as a “draw ratio”, rather than a strain: in this case, extrapolation of the tangent is carried out to a draw ratio of zero, rather than a strain of -1. Graphical construction indicating criteria for neck formation and neck stabilization.
The Mayo–Lewis equation or copolymer equation in polymer chemistry describes the ... The reactivity ratio for each propagating chain end is defined as the ratio of ...
Polymer morphology is a microscale property that is largely dictated by the amorphous or crystalline portions of the polymer chains and their influence on each other. Microscopy techniques are especially useful in determining these microscale properties, as the domains created by the polymer morphology are large enough to be viewed using modern ...
Draw resonance has not been found to be a function of the flow rate, however. A polymer melt approaching a Newtonian fluid such as PET can have a drawdown ratio of around 20, whereas highly shear thinning and viscoelastic polymer melts such as polyethylene, polystyrene, and polypropylene may have critical drawdown ratios as low as 3.
The synthesis and processing of polyacetylene films affects the properties. Increasing the catalyst ratio creates thicker films with a greater draw ratio, allowing them to be stretched further. [8] Lower catalyst loadings leads to the formation of dark red gels, which can be converted to films by cutting and pressing between glass plates. [20]
In synthetic polymers, it can vary greatly due to reactant ratio, how close the polymerization went to completion, etc. For typical addition polymerization , Đ can range around 5 to 20. For typical step polymerization, most probable values of Đ are around 2 — Carothers' equation limits Đ to values of 2 and below.
The degree of polymerization, or DP, is the number of monomeric units in a macromolecule or polymer or oligomer molecule. [1] [2] [3]For a homopolymer, there is only one type of monomeric unit and the number-average degree of polymerization is given by ¯ ¯ = ¯, where ¯ is the number-average molecular weight and is the molecular weight of the monomer unit.
Most materials have Poisson's ratio values ranging between 0.0 and 0.5. For soft materials, [1] such as rubber, where the bulk modulus is much higher than the shear modulus, Poisson's ratio is near 0.5. For open-cell polymer foams, Poisson's ratio is near zero, since the cells tend to collapse in compression.