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Furthermore, theories have been put forward to take into account the effects of vibronic coupling on electron transfer, in particular, the PKS theory of electron transfer. [10] In proteins, ET rates are governed by the bond structures: the electrons, in effect, tunnel through the bonds comprising the chain structure of the proteins. [11]
In theoretical chemistry, Marcus theory is a theory originally developed by Rudolph A. Marcus, starting in 1956, to explain the rates of electron transfer reactions – the rate at which an electron can move or jump from one chemical species (called the electron donor) to another (called the electron acceptor). [1]
The strongest bonds are formed by the sharing or transfer of electrons between atoms, allowing the formation of molecules. [17] Within a molecule, electrons move under the influence of several nuclei, and occupy molecular orbitals; much as they can occupy atomic orbitals in isolated atoms. [128]
Electrons in atoms and molecules can change (make transitions in) energy levels by emitting or absorbing a photon (of electromagnetic radiation), whose energy must be exactly equal to the energy difference between the two levels. Electrons can also be completely removed from a chemical species such as an atom, molecule, or ion.
Heat transfer physics analyses may involve multiple scales (e.g., BTE using interaction rate from ab initio or classical MD) with states and kinetic related to thermal energy storage, transport and transformation. So, heat transfer physics covers the four principal energy carries and their kinetics from classical and quantum mechanical ...
A Proton-coupled electron transfer (PCET) is a chemical reaction that involves the transfer of electrons and protons from one atom to another. The term was originally coined for single proton, single electron processes that are concerted, [ 1 ] but the definition has relaxed to include many related processes.
Autotrophs can use this process to supply reducing power for inorganic carbon fixation. Reverse electron transfer ( RET ) is the process that can occur in respiring mitochondria , when a small fraction of electrons from reduced ubiquinol is driven upstream by the membrane potential towards mitochondrial complex I .
In chemistry, charge-transfer (CT) complex, or electron donor-acceptor complex, describes a type of supramolecular assembly of two or more molecules or ions. The assembly consists of two molecules that self-attract through electrostatic forces, i.e., one has at least partial negative charge and the partner has partial positive charge, referred ...