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  2. Mass spectrometry - Wikipedia

    en.wikipedia.org/wiki/Mass_spectrometry

    Mass spectrometry data analysis is specific to the type of experiment producing the data. General subdivisions of data are fundamental to understanding any data. Many mass spectrometers work in either negative ion mode or positive ion mode. It is very important to know whether the observed ions are negatively or positively charged.

  3. Ion funnel - Wikipedia

    en.wikipedia.org/wiki/Ion_funnel

    The introduction of the ion funnel greatly reduced the amount of ions lost during experiments by guiding ions towards a desired destination, [8] and through modification of the number of inlets is also able to increases sensitivity of measurements taken by the mass spectrometer. Multiple inlets allow multiple electrospray emitters, reducing the ...

  4. Chemical ionization - Wikipedia

    en.wikipedia.org/wiki/Chemical_ionization

    A schematic diagram of chemical ionization source. Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. [1] [2] This was first introduced by Burnaby Munson and Frank H. Field in 1966. [3] This technique is a branch of gaseous ion-molecule chemistry. [2]

  5. Direct analysis in real time - Wikipedia

    en.wikipedia.org/wiki/Direct_analysis_in_real_time

    In mass spectrometry, direct analysis in real time (DART) is an ion source that produces electronically or vibronically excited-state species from gases such as helium, argon, or nitrogen that ionize atmospheric molecules or dopant molecules. The ions generated from atmospheric or dopant molecules undergo ion-molecule reactions with the sample ...

  6. Mass spectral interpretation - Wikipedia

    en.wikipedia.org/wiki/Mass_spectral_interpretation

    [1] [2] Mass spectra is a plot of relative abundance against mass-to-charge ratio. It is commonly used for the identification of organic compounds from electron ionization mass spectrometry. [3] [4] Organic chemists obtain mass spectra of chemical compounds as part of structure elucidation and the analysis is part of many organic chemistry ...

  7. Mass spectrum - Wikipedia

    en.wikipedia.org/wiki/Mass_spectrum

    A mass spectrum is a histogram plot of intensity vs. mass-to-charge ratio (m/z) in a chemical sample, [1] usually acquired using an instrument called a mass spectrometer. Not all mass spectra of a given substance are the same; for example, some mass spectrometers break the analyte molecules into fragments ; others observe the intact molecular ...

  8. Ion source - Wikipedia

    en.wikipedia.org/wiki/Ion_source

    Simply introducing the matrix-analyte sample to the inlet aperture of an atmospheric pressure ionization mass spectrometer produces abundant ions. Compounds at least as large as bovine serum albumin [66 kDa] can be ionized with this method. [53] In this method, the inlet to the mass spectrometer can be considered the ion source.

  9. Field desorption - Wikipedia

    en.wikipedia.org/wiki/Field_desorption

    Schematic of field desorption ionization with emitter at left and mass spectrometer at right. Field desorption (FD) is a method of ion formation used in mass spectrometry (MS) in which a high-potential electric field is applied to an emitter with a sharp surface, such as a razor blade, or more commonly, a filament from which tiny "whiskers" have formed.