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The relationship between frequency (proportional to energy) and wavenumber or velocity (proportional to momentum) is called a dispersion relation. Light waves in a vacuum have linear dispersion relation between frequency: ω = c k {\displaystyle \omega =ck} .
Relationship between wavelength, angular wavelength, and other wave properties. A quantity related to the wavelength is the angular wavelength (also known as reduced wavelength), usually symbolized by ƛ ("lambda-bar" or barred lambda). It is equal to the ordinary wavelength reduced by a factor of 2π (ƛ = λ/2π), with SI units of meter per ...
For example, a wavenumber in inverse centimeters can be converted to a frequency expressed in the unit gigahertz by multiplying by 29.979 2458 cm/ns (the speed of light, in centimeters per nanosecond); [5] conversely, an electromagnetic wave at 29.9792458 GHz has a wavelength of 1 cm in free space.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The name "dispersion relation" originally comes from optics. It is possible to make the effective speed of light dependent on wavelength by making light pass through a material which has a non-constant index of refraction, or by using light in a non-uniform medium such as a waveguide. In this case, the waveform will spread over time, such that ...
This equation is known as the Planck relation. Additionally, using equation f = c/λ, = where E is the photon's energy; λ is the photon's wavelength; c is the speed of light in vacuum; h is the Planck constant; The photon energy at 1 Hz is equal to 6.626 070 15 × 10 −34 J, which is equal to 4.135 667 697 × 10 −15 eV.
For example, many hydrogen atoms emit a radio wave photon that has a wavelength of 21.12 cm. Also, frequencies of 30 Hz and below can be produced by and are important in the study of certain stellar nebulae [ 4 ] and frequencies as high as 2.9 × 10 27 Hz have been detected from astrophysical sources.
As an example, water has a refractive index of 0.999 999 74 = 1 − 2.6 × 10 −7 for X-ray radiation at a photon energy of 30 keV (0.04 nm wavelength). [ 21 ] An example of a plasma with an index of refraction less than unity is Earth's ionosphere .