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Tribromide is the anion with the chemical formula Br 3 −, or salts containing it: . Tetrabutylammonium tribromide; Tetrabromophosphonium tribromide; Pyridinium perbromide; Sodium and potassium tribromides can be prepared by reacting NaBr or KBr with aqueous bromine.
Phosphorus tribromide, like PCl 3 and PF 3, has both properties of a Lewis base and a Lewis acid. For example, with a Lewis acid such as boron tribromide it forms stable 1 :1 adducts such as Br 3 B · PBr 3. At the same time PBr 3 can react as an electrophile or Lewis acid in many of its reactions, for example with amines.
Boron tribromide, BBr 3, is a colorless, fuming liquid compound containing boron and bromine. Commercial samples usually are amber to red/brown, due to weak bromine contamination. Commercial samples usually are amber to red/brown, due to weak bromine contamination.
The Lewis acidity of all the gallium trihalides, GaBr 3 included, has been extensively studied thermodynamically, and the basicity of GaBr 3 has been established with a number of donors. [2] GaBr 3 is capable of accepting an additional Br − ion or unevenly splitting its dimer to form [GaBr 4] −, a tetrahedral ion of which crystalline salts ...
Nitrogen tribromide reacts instantly with ammonia in dichloromethane solution at −87 °C to yield NBrH 2. [7] NBr 3 + 2 NH 3 → 3 NH 2 Br. It also reacts with iodine in dichloromethane solution at −87 °C to produce NBr 2 I, which is a red-brown solid that stable up to -20 °C. [7] NBr 3 + I 2 → NBr 2 I + IBr
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
Antimony tribromide has two crystalline forms, both having orthorhombic symmetries. When a warm carbon disulfide solution of SbBr 3 is rapidly cooled, it crystallizes into the needle-like α-SbBr 3, which then slowly converts to the more stable β form. [2] Antimony tribromide hydrolyzes in water to form hydrobromic acid and antimony trioxide:
Arsenic tribromide can be prepared by the direct bromination of arsenic powder. Alternatively, arsenic(III) oxide can be used as the precursor in the presence of elemental sulfur: 2 As 2 O 3 + 3 S + 6 Br 2 → 4 AsBr 3 + 3 SO 2. Arsenic tribromide is a highly water soluble crystalline arsenic source for uses compatible with bromides and lower ...