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PbO + 2 HNO 3 (concentrated) → Pb(NO 3) 2 ↓ + H 2 O. It may also be obtained by evaporation of the solution obtained by reacting metallic lead with dilute nitric acid. [11] Pb + 4 HNO 3 → Pb(NO 3) 2 + 2 NO 2 + 2 H 2 O. Solutions and crystals of lead(II) nitrate are formed in the processing of lead–bismuth wastes from lead refineries. [12]
Lead sesquioxide, Pb 2 O 3, which is a lead (II,IV) oxide as well (lead(II) metaplumbate(IV) [Pb 2+][PbO 2− 3]), reddish yellow Pb 12 O 19 , monoclinic, dark-brown or black crystals The so-called black lead oxide , which is a mixture of PbO and fine-powdered Pb metal and used in the production of lead–acid batteries .
pb 3 o 4 + 4 hno 3 → pbo 2 + 2 pb(no 3) 2 + 2 h 2 o With iron oxides and with elemental iron , lead(II,IV) oxide forms insoluble iron(II) and iron(III) plumbates , which is the basis of the anticorrosive properties of lead-based paints applied to iron objects.
PbO 2 + 2 OH − + 2 H 2 O → Pb(OH) 2− 6. Lead also has an oxide with mixed +2 and +4 oxidation states, red lead (Pb 3 O 4), also known as minium. Lead readily forms an equimolar alloy with sodium metal that reacts with alkyl halides to form organometallic compounds of lead such as tetraethyllead. [4]
The capped square antiprismatic anion [Pb 9] 4− from [K(18-crown-6)] 2 K 2 Pb 9 ·(en) 1.5 [82] Some lead compounds exist in formal oxidation states other than +4 or +2. Lead(III) may be obtained, as an intermediate between lead(II) and lead(IV), in larger organolead complexes; this oxidation state is not stable, as both the lead(III) ion and ...
2 Pb(NO 3) 2 → 2 PbO + 4 NO 2 + O 2 PbCO 3 → PbO + CO 2. PbO is produced on a large scale as an intermediate product in refining raw lead ores into metallic lead. The usual lead ore is galena (lead(II) sulfide). At a temperature of around 1,000 °C (1,800 °F) in air, the sulfide converted to the oxide: [4] 2 PbS + 2 O 2 → 2 PbO + 2 SO 2
When heated to 150–180 °C, it decomposes with autooxidation to plutonium (VI) with the formation of plutonyl nitrate (PuO 2 (NO 3) 2).Upon evaporation of concentrated nitric acid solutions of plutonium nitrate and alkali metal nitrates, double nitrates of the composition M 2 [Pu(NO 3) 6] are formed, where M = Cs +, Rb +, K +, Tl +, NH 4 +, analogous to ceric ammonium nitrate.
A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite (NO − 2) and nitrate (NO − 3) anions.They are mixed-anion compounds, and they are mixed-valence compounds.