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The millimeter of mercury by definition is 133.322387415 Pa [5] (13.5951 g/cm 3 × 9.80665 m/s 2 × 1 mm), which is approximated with known accuracies of density of mercury and standard gravity. The torr is defined as 1 / 760 of one standard atmosphere, while the atmosphere is defined as 101325 pascals.
In chemistry, IUPAC changed its definition of standard temperature and pressure in 1982: [1] [2] Until 1982, STP was defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of exactly 1 atm (101.325 kPa).
The standard atmosphere was originally defined as the pressure exerted by a 760 mm column of mercury at 0 °C (32 °F) and standard gravity (g n = 9.806 65 m/s 2). [2] It was used as a reference condition for physical and chemical properties, and the definition of the centigrade temperature scale set 100 °C as the boiling point of water at this pressure.
Atmospheric pressure, also known as air pressure or barometric pressure (after the barometer), is the pressure within the atmosphere of Earth.The standard atmosphere (symbol: atm) is a unit of pressure defined as 101,325 Pa (1,013.25 hPa), which is equivalent to 1,013.25 millibars, [1] 760 mm Hg, 29.9212 inches Hg, or 14.696 psi. [2]
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
The zeroth law is of importance in thermometry, because it implies the existence of temperature scales. In practice, C is a thermometer, and the zeroth law says that systems that are in thermodynamic equilibrium with each other have the same temperature. The law was actually the last of the laws to be formulated. First law of thermodynamics
In physics and thermodynamics, the Redlich–Kwong equation of state is an empirical, algebraic equation that relates temperature, pressure, and volume of gases. It is generally more accurate than the van der Waals equation and the ideal gas equation at temperatures above the critical temperature .
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...