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Catalytic converter prototypes were first designed in France at the end of the 19th century, when only a few thousand "oil cars" were on the roads; these prototypes had inert clay-based materials coated with platinum, rhodium, and palladium and sealed into a double metallic cylinder. [6]
The largest use of palladium today is in catalytic converters. [41] Palladium is also used in jewelry, dentistry, [41] [42] watch making, blood sugar test strips, aircraft spark plugs, surgical instruments, and electrical contacts. [43] Palladium is also used to make some professional transverse (concert or classical) flutes. [44]
Palladium is found as a free metal and alloyed with platinum and gold with platinum group metals in placer deposits of the Ural Mountains of Eurasia, Australia, Ethiopia, South and North America. However it is commercially produced from nickel- copper deposits found in South Africa and Ontario, Canada .
In catalytic converters used on automobiles, the combustion of leaded gasoline produces elemental lead, lead(II) oxide, lead(II) chloride, and lead(II) bromide. Lead alloys with the metals present in the catalyst, while lead oxides and halides coat the catalyst's surfaces, reducing the converter's ability to reduce NOx emissions.
Carl D. Keith (left) and John J. Mooney at the award ceremony for the National Medal of Technology and Innovation for the invention, application and commercialization of the three-way catalytic converter (2003) The 1970 amendments to the Clean Air Act required significant reductions in hydrocarbon, carbon monoxide and nitrogen oxide emissions.
Inside a recombiner there are plates or pellets that are coated with platinum or palladium catalyst. On the surface of the catalyst, hydrogen and oxygen molecules react chemically at low temperature and low hydrogen concentration. The reaction generates steam. The reaction starts spontaneously when the hydrogen concentration reaches 1–2 percent.