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As shown in the figure, the electron's speed is reduced, and the mercury atom becomes "excited". A short time later, the 4.9 eV of energy that was deposited into the mercury atom is released as ultraviolet light that has a wavelength of precisely 254 nm. Following light emission, the mercury atom returns to its original, unexcited state. [16] [17]
Atoms can be excited by heat, electricity, or light. The hydrogen atom provides a simple example of this concept.. The ground state of the hydrogen atom has the atom's single electron in the lowest possible orbital (that is, the spherically symmetric "1s" wave function, which, so far, has been demonstrated to have the lowest possible quantum numbers).
A fourth rule is that when an electron undergoes a transition, the spin state of the molecule/atom that contains the electron must be conserved. [8] Under some circumstances, certain selection rules may be broken and excited electrons may make "forbidden" transitions. The spectral lines associated with such transitions are known as forbidden lines.
A Jablonski diagram showing the excitation of molecule A to its singlet excited state (1 A*) followed by intersystem crossing to the triplet state (3 A) that relaxes to the ground state by phosphorescence. It was used to describe absorption and emission of light by fluorescents.
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The electron configuration of the new state may result in a shift of the equilibrium position of the nuclei constituting the molecule. In Figure 3 this shift in nuclear coordinates between the ground and the first excited state is labeled as q 01.
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Any other configuration is an excited state. As an example, the ground state configuration of the sodium atom is 1s 2 2s 2 2p 6 3s 1, as deduced from the Aufbau principle (see below). The first excited state is obtained by promoting a 3s electron to the 3p subshell, to obtain the 1s 2 2s 2 2p 6 3p 1 configuration, abbreviated as the 3p level ...