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Le Chatelier–Braun principle analyzes the qualitative behaviour of a thermodynamic system when a particular one of its externally controlled state variables, say , changes by an amount , the 'driving change', causing a change , the 'response of prime interest', in its conjugate state variable , all other externally controlled state variables remaining constant.
Le Chatelier was born on 8 October 1850 in Paris and was the son of French materials engineer Louis Le Chatelier and Louise Durand. His father was an influential figure who played important roles in the birth of the French aluminium industry, the introduction of the Martin-Siemens processes into the iron and steel industries, and the rise of railway transportation.
According to Le Chatelier's principle, the addition of acetate ions from sodium acetate will suppress the ionization of acetic acid and shift its equilibrium to the left. Thus the percent dissociation of the acetic acid will decrease, and the pH of the solution will increase.
Le Chatelier's principle states that the system opposes changes in conditions from equilibrium states, i.e. there is an opposition to change the state of an equilibrium reaction. Transforming one structure to another requires the input of energy to cross an energy barrier; this can come from the intrinsic energy of the molecules themselves, or ...
The of a mixture can be evaluated using the Le Chatelier mixing rule if the of the components are known: [2] = Where is the lower flammability of the ...
Jean le Rond d'Alembert: Dalton's law of partial pressure: Thermodynamics: John Dalton: Darcy's law: Fluid mechanics: Henry Darcy: De Bruijn–Erdős theorem: Mathematics: Nicolaas Govert de Bruijn and Paul Erdős: De Morgan's law: Logic: Augustus De Morgan: Dermott's law: Celestial mechanics: Stanley Dermott: Descartes's theorem: Geometry ...
Le Châtelier's principle (1884) predicts the behavior of an equilibrium system when changes to its reaction conditions occur. If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to partially reverse the change. For example, adding more S (to the chemical reaction above) from the outside will ...
The pressure dependence can be explained with the Le Chatelier's principle. For example, an increase in pressure due to decreasing volume causes the reaction to shift ...