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A state function describes equilibrium states of a system, thus also describing the type of system. A state variable is typically a state function so the determination of other state variable values at an equilibrium state also determines the value of the state variable as the state function at that state. The ideal gas law is a good example ...
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Thermodynamic temperature is a specifically thermodynamic concept, while the original directly measureable state variables are defined by ordinary physical measurements, without reference to thermodynamic concepts; for this reason, it is helpful to regard thermodynamic temperature as a state function.
The following state functions are of primary concern in chemical thermodynamics: Internal energy (U) Enthalpy (H) Entropy (S) Gibbs free energy (G) Most identities in chemical thermodynamics arise from application of the first and second laws of thermodynamics, particularly the law of conservation of energy, to these state functions.
More generally, condensation refers to the appearance of macroscopic occupation of one or several states: for example, in BCS theory, a superconductor is a condensate of Cooper pairs. [1] As such, condensation can be associated with phase transition, and the macroscopic occupation of the state is the order parameter.
Ferromagnetism: A state of matter with spontaneous magnetization. Antiferromagnetism: A state of matter in which the neighboring spin are antiparallel with each other, and there is no net magnetization. Ferrimagnetism: A state in which local moments partially cancel. Altermagnetism: A state with zero net magnetization and spin-split electronic ...
The steady state approximation, [1] occasionally called the stationary-state approximation or Bodenstein's quasi-steady state approximation, involves setting the rate of change of a reaction intermediate in a reaction mechanism equal to zero so that the kinetic equations can be simplified by setting the rate of formation of the intermediate equal to the rate of its destruction.
An example of an equation of state correlates densities of gases and liquids to temperatures and pressures, known as the ideal gas law, which is roughly accurate for weakly polar gases at low pressures and moderate temperatures. This equation becomes increasingly inaccurate at higher pressures and lower temperatures, and fails to predict ...