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, Ca 2+, and Sc 3+ and the anions Cl −, S 2−, and P 3− are all isoelectronic with the Ar atom. CO, CN −, N 2, and NO + are isoelectronic because each has two atoms triple bonded together, and due to the charge have analogous electronic configurations (N − is identical in electronic configuration to O so CO is identical electronically ...
In physics, mirror nuclei are a pair of isobars of two different elements where the number of protons of isobar one (Z 1) equals the number of neutrons of isobar two (N 2) and the number of protons of isotope two (Z 2) equals the number of neutrons in isotope one (N 1); in short: Z 1 = N 2 and Z 2 = N 1.
Isolobal compounds are analogues to isoelectronic compounds that share the same number of valence electrons and structure. A graphic representation of isolobal structures, with the isolobal pairs connected through a double-headed arrow with half an orbital below, is found in Figure 1. Figure 1: Basic example of the isolobal analogy
In chemistry, bond order is a formal measure of the multiplicity of a covalent bond between two atoms. As introduced by Gerhard Herzberg, [1] building off of work by R. S. Mulliken and Friedrich Hund, bond order is defined as the difference between the numbers of electron pairs in bonding and antibonding molecular orbitals.
Example: C 2 B 7 H 13. Electron count = 2 × C + 7 × B + 13 × H = 2 × 4 + 7 × 3 + 13 × 1 = 42 Since n in this case is 9, 4n + 6 = 42, the cluster is arachno. The bookkeeping for deltahedral clusters is sometimes carried out by counting skeletal electrons instead of the total number of electrons.
In this example, the cyanide ligands are "innocent", i.e., they have a charge of −1 each, −5 total. To balance the fragment's overall charge, the charge on {CrNO} is thus +2 (−3 = −5 + 2). Using the neutral electron counting scheme, Cr has 6 d electrons and NO· has one electron for a total of 7. Two electrons are subtracted to take ...
In chemistry, ion association is a chemical reaction whereby ions of opposite electric charge come together in solution to form a distinct chemical entity. [1] [2] Ion associates are classified, according to the number of ions that associate with each other, as ion pairs, ion triplets, etc. Ion pairs are also classified according to the nature of the interaction as contact, solvent-shared or ...
), have two odd–even stable isotopes each. This makes a total of 30×1 + 9×2 = 48 stable odd–even isotopes. The lightest example of this type of nuclide is 1 1 H (protium) as zero is an even number while the heaviest example is 205 81 Tl. There are also five primordial long-lived radioactive odd–even isotopes, 87 37 Rb, [9] 115 49 In ...