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Tetraoxygen was first predicted in 1924 by Gilbert N. Lewis, who proposed it as an explanation for the failure of liquid oxygen to obey Curie's law. [1] Though not entirely inaccurate, computer simulations indicate that although there are no stable O 4 molecules in liquid oxygen, O 2 molecules do tend to associate in pairs with antiparallel spins, forming transient O 4 units. [2]
Liquid oxygen has a clear cyan color and is strongly paramagnetic: it can be suspended between the poles of a powerful horseshoe magnet. [2] Liquid oxygen has a density of 1.141 kg/L (1.141 g/ml), slightly denser than liquid water, and is cryogenic with a freezing point of 54.36 K (−218.79 °C; −361.82 °F) and a boiling point of 90.19 K (−182.96 °C; −297.33 °F) at 1 bar (14.5 psi).
Liquid water can be split into the elements hydrogen and oxygen by passing an electric current through it—a process called electrolysis. The decomposition requires more energy input than the heat released by the inverse process (285.8 kJ/ mol , or 15.9 MJ/kg).
Its bulk properties partly result from the interaction of its component atoms, oxygen and hydrogen, with atoms of nearby water molecules. Hydrogen atoms are covalently bonded to oxygen in a water molecule but also have an additional attraction (about 23.3 kJ·mol −1 per hydrogen atom) to an adjacent oxygen atom in a separate molecule. [2]
2 O) is a simple triatomic bent molecule with C 2v molecular symmetry and bond angle of 104.5° between the central oxygen atom and the hydrogen atoms. Despite being one of the simplest triatomic molecules , its chemical bonding scheme is nonetheless complex as many of its bonding properties such as bond angle , ionization energy , and ...
[16] [17] [18] A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O 2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H 2 O). A molecule is the smallest unit of a substance that ...
A molecule may be homonuclear, that is, it consists of atoms of one chemical element, e.g. two atoms in the oxygen molecule (O 2); or it may be heteronuclear, a chemical compound composed of more than one element, e.g. water (two hydrogen atoms and one oxygen atom; H 2 O).
Atmospheric electricity utilization for the chemical reaction in which water is separated into oxygen and hydrogen. (Image via: Vion, US patent 28793. June 1860.) Electrolyser front with electrical panel in foreground. Electrolysis of water is the decomposition of water (H 2 O) into oxygen (O 2) and hydrogen (H 2): [2] Water electrolysis ship ...