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HKUST-1 (HKUST ⇒ Hong Kong University of Science and Technology), [1] which is also called MOF-199, [2] is a material in the class of metal-organic frameworks (MOFs). Metal-organic frameworks are crystalline materials, in which metals are linked by ligands (so-called linker molecules) to form repeating coordination motives extending in three ...
As one might expect, given the greater Lewis acidity of Cr(III) vs. Cu(II), MIL-101 is much more active than HKUST-1 as a catalyst for the cyanosilylation of aldehydes. Additionally, the Kaskel group observed that the catalytic sites of MIL-101, in contrast to those of HKUST-1, are immune to unwanted reduction by benzaldehyde.
The HKUST Learning Commons provides ~600 seats and has 5 zones: Group Study, Open Study, Refreshment, Teaching, and The Creative Media Zone. [9] The Library and its staff were very active in supporting the university in the University Grants Committee (Hong Kong)'s Hong Kong Research Assessment Exercise of 2014. [10]
All full-time registered UG students and in-time [note 2] full-time HKUST research postgraduate students (RPgs) of the university are eligible to apply for student housing. Under the current policy, all local UG students are guaranteed at least one semester of hall residence in their first year of study upon application, whilst their non-local ...
[1] Cr(CO) 6 reacts directly with benzene and other arenes to give the piano stool complexes Cr(C 6 R 6)(CO) 3. [5] The carbonyls of Mo and W behave comparably. The method works particularly well with electron-rich arenes (e.g., anisole, mesitylene). The reaction has been extended to the synthesis of [Mn(C 6 R 6)(CO) 3] +: [6]
Click chemistry is an approach to chemical synthesis that emphasizes efficiency, simplicity, selectivity, and modularity in chemical processes used to join molecular building blocks. It includes both the development and use of "click reactions", a set of simple, biocompatible chemical reactions that meet specific criteria like high yield, fast ...
The solid-state reaction route is the most widely used method for the preparation of polycrystalline solids from a mixture of solid starting materials. Solids do not react together at room temperature over normal time scales and it is necessary to heat them to much higher temperatures, often to 1000 to 1500 °C, in order for the reaction to occur at an appreciable rate.
In organic chemistry, the Arndt–Eistert reaction is the conversion of a carboxylic acid to its homologue.It is named for the German chemists Fritz Arndt (1885–1969) and Bernd Eistert (1902–1978).