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In physics and chemistry, the Lyman series is a hydrogen spectral series of transitions and resulting ultraviolet emission lines of the hydrogen atom as an electron goes from n ≥ 2 to n = 1 (where n is the principal quantum number), the lowest energy level of the electron (groundstate). The transitions are named sequentially by Greek letters ...
The spectral series of hydrogen, on a logarithmic scale. The emission spectrum of atomic hydrogen has been divided into a number of spectral series, with wavelengths given by the Rydberg formula. These observed spectral lines are due to the electron making transitions between two energy levels in an atom.
Lyman-alpha, typically denoted by Ly-α, is a spectral line of hydrogen (or, more generally, of any one-electron atom) in the Lyman series. It is emitted when the atomic electron transitions from an n = 2 orbital to the ground state ( n = 1), where n is the principal quantum number .
The photon absorption process leading to the ionization of atomic hydrogen can occur in reverse: an electron and a proton can collide and form atomic hydrogen. If the two particles were traveling slowly (so that kinetic energy can be ignored), then the photon the atom emits upon its creation will theoretically be 13.6 eV (in reality, the energy ...
A hydrogen molecule can absorb a far-ultraviolet photon (11.2 eV < energy of the photon < 13.6 eV) and make a transition from the ground electronic state X to excited state B (Lyman) or C (Werner). Radiative decay occurs rapidly. 10–15% of the decays occur into the vibrational continuum. This means that the hydrogen molecule has dissociated.
At even higher field strengths, comparable to the strength of the atom's internal field, the electron coupling is disturbed and the spectral lines rearrange. This is called the Paschen–Back effect. In modern scientific literature, these terms are rarely used, with a tendency to use just the "Zeeman effect".
From the first excited state, electrons can reach the ground state n = 1 through two pathways: Decay from the 2p state by emitting a Lyman-α photon . This photon will almost always be reabsorbed by another hydrogen atom in its ground state.
A hydrogen atom with proton and electron spins aligned (top) undergoes a flip of the electron spin, resulting in emission of a photon with a 21 cm wavelength (bottom) The hydrogen line, 21 centimeter line, or H I line [a] is a spectral line that is created by a change in the energy state of solitary, electrically neutral hydrogen atoms.