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The Frasch process is a method to extract sulfur from underground deposits by taking advantage of the low melting point of sulfur. It is the only industrial method of recovering sulfur from elemental deposits. [1] Most of the world's sulfur was obtained this way until the late 20th century, when sulfur recovered from petroleum and gas sources ...
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The contact process is a method of producing sulfuric acid in the high concentrations needed for industrial processes. Platinum was originally used as the catalyst for this reaction; however, because it is susceptible to reacting with arsenic impurities in the sulfur feedstock, vanadium(V) oxide (V 2 O 5) has since been preferred.
The vast majority of the 64,000,000 tonnes of sulfur produced worldwide in 2005 was byproduct sulfur from refineries and other hydrocarbon processing plants. [3] [4] [5] Sulfur is used for manufacturing sulfuric acid, medicine, cosmetics, fertilizers and rubber products. Elemental sulfur is used as fertilizer and pesticide.
The sulfur is recovered as concentrated sulfuric acid and the nitrogen oxides are reduced to free nitrogen. The process is based on the well-known wet sulfuric acid process (WSA), a process for recovering sulfur from various process gasses in the form of commercial quality sulfuric acid (H 2 SO 4 ).
Desulfurization or desulphurisation is a chemical process for the removal of sulfur from a material. [1] The term usually refers to the removal of sulfur from a molecule or a material by hydrogenolysis: [2] R 2 S + 2 H 2 → 2RH + H 2 S. Hydrogen is the ultimate sulfur acceptor. As applied to oil refinery streams, the conversion is known as ...
The lead chamber process was an industrial method used to produce sulfuric acid in large quantities. It has been largely supplanted by the contact process.. In 1746 in Birmingham, England, John Roebuck began producing sulfuric acid in lead-lined chambers, which were stronger and less expensive and could be made much larger than the glass containers that had been used previously.
For the ores Cu 2 S and ZnS , balanced equations for the roasting are: 2 Cu 2 S + 3 O 2 → 2 Cu 2 O + 2 SO 2 2 ZnS + 3 O 2 → 2 ZnO + 2 SO 2. The gaseous product of sulfide roasting, sulfur dioxide (SO 2) is often used to produce sulfuric acid. Many sulfide minerals contain other components such as arsenic that are released into the environment.