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Liquid bleach, often called just bleach, is a common chemical household product that consists of a dilute solution of sodium hypochlorite (NaClO) and other secondary ingredients. It is a chlorine releasing bleaching agent widely used to whiten clothes and remove stains, as a disinfectant to kill germs , and for several other uses.
The process has a high energy consumption, for example around 2,500 kWh (9,000 MJ) of electricity per tonne of sodium hydroxide produced. Because the process yields equivalent amounts of chlorine and sodium hydroxide (two moles of sodium hydroxide per mole of chlorine), it is necessary to find a use for these products in the same proportion ...
Dakin's solution is a dilute solution of sodium hypochlorite (0.4% to 0.5%) and other stabilizing ingredients, traditionally used as an antiseptic, e.g. to cleanse wounds in order to prevent infection. [1] The preparation was for a time called also Carrel–Dakin solution or Carrel–Dakin fluid. [2]
Near the end of the nineteenth century, E. S. Smith patented the chloralkali process: a method of producing sodium hypochlorite involving the electrolysis of brine to produce sodium hydroxide and chlorine gas, which then mixed to form sodium hypochlorite. [35] [33] [36] The key reactions are: 2 Cl − → Cl 2 + 2 e − (at the anode)
Bleach is the generic name for any chemical product that is used industrially or domestically to remove color from (i.e. to whiten) fabric or fiber (in a process called bleaching) or to disinfect after cleaning. It often refers specifically to a dilute solution of sodium hypochlorite, also called "liquid bleach".
Chlorine is a respiratory irritant that attacks mucous membranes and burns the skin. As little as 3.53 ppm can be detected as an odor, and 1000 ppm is likely to be fatal after a few deep breaths. Exposure to chlorine has been limited to 0.5 ppm (8-hour time-weighted average—38-hour week) by the U.S. OSHA. [9]
If the solution near the anode is acidic then it will contain elemental chlorine, if it is alkaline then it will comprise sodium hydroxide. The key to delivering a powerful sanitising agent is to form hypochlorous acid without elemental chlorine - this occurs at around neutral pH. Hypochlorous is a weak acid and an oxidizing agent. [3]
Chlorine can be manufactured by the electrolysis of a sodium chloride solution , which is known as the Chloralkali process. The production of chlorine results in the co-products caustic soda (sodium hydroxide, NaOH) and hydrogen gas (H 2). These two products, as well as chlorine itself, are highly reactive.