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Acrylonitrile is an organic compound with the formula CH 2 CHCN and the structure H 2 C=CH−C≡N. It is a colorless, volatile liquid although commercial samples can be yellow due to impurities. It has a pungent odor of garlic or onions. [4] Its molecular structure consists of a vinyl group (−CH=CH 2) linked to a nitrile (−C≡N).
Lewis structure of a water molecule. Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDs) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule.
Acrylonitrile is commonly employed as a comonomer with styrene, e.g. acrylonitrile, styrene and acrylate plastics. Labelling of items of clothing with acrylic (see acrylic fiber) means the polymer consists of at least 85% acrylonitrile as the monomer. A typical comonomer is vinyl acetate, which can be solution-spun readily to obtain fibers that ...
Acetonitrile, often abbreviated MeCN (methyl cyanide), is the chemical compound with the formula CH 3 CN and structure H 3 C−C≡N. This colourless liquid is the simplest organic nitrile (hydrogen cyanide is a simpler nitrile, but the cyanide anion is not classed as organic). It is produced mainly as a byproduct of acrylonitrile manufacture.
Chemical structure of the vinyl functional group. In organic chemistry , a vinyl group (abbr. Vi ; [ 1 ] IUPAC name : ethenyl group [ 2 ] ) is a functional group with the formula −CH=CH 2 . It is the ethylene (IUPAC name: ethene) molecule ( H 2 C=CH 2 ) with one fewer hydrogen atom.
The main industrial route to this nitrile is the hydrogenation of acrylonitrile. It is also prepared by the ammoxidation of propanol (propionaldehyde can also be used instead): [7] CH 3 CH 2 CH 2 OH + O 2 + NH 3 → CH 3 CH 2 C≡N + 3 H 2 O. Propionitrile is a byproduct of the electrodimerisation of acrylonitrile to adiponitrile.
The term alcohol originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. The suffix -ol appears in the International Union of Pure and Applied Chemistry (IUPAC) chemical name of all substances where the hydroxyl group is the functional group with the ...
The β-carbon atom that is furthest from the nitrile group is positively polarized and therefore binds the heteroatom on the nucleophile. Acrylonitrile is a Michael acceptor. [2] The reaction is normally catalyzed by a base. [3] Tris(cyanoethyl)phosphine is produced by the cyanoethylation of phosphine. [4]