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Iron gall ink (also known as common ink, standard ink, oak gall ink or iron gall nut ink) is a purple-black or brown-black ink made from iron salts and tannic acids from vegetable sources. It was the standard ink formulation used in Europe for the 1400-year period between the 5th and 19th centuries, remained in widespread use well into the 20th ...
Not only does it mold quickly in high humidity environments, but early forms of ink that were commonly used on papyrus could simply be washed off without leaving a trace. It is believed that "Iron gall inks were devised to overcome this disadvantage," however even these inks can be wiped off fairly thoroughly if they are scrubbed (Langwell 43).
Other consequences of aqueous treatment are a change of ink texture or formation of plaque on the surface of the ink (Reibland & de Groot 1999). Iron gall inks require storage in a stable environment, because fluctuating relative humidity increases the rate that formic acid, acetic acid, and furan derivatives form in the material the ink was ...
Iron gall ink was used in fountain pens when they were invented but has the disadvantage of causing corrosion to metal parts. Modern formulations of iron gall ink are somewhat less corrosive and are still occasionally used in applications that require permanence. Bottle of green ink. Red inks usually contain the dye eosin. Blue inks often ...
Thermolysis of iron(II) sulfate begins at about 680 °C (1,256 °F). 2 FeSO 4 Fe 2 O 3 + SO 2 + SO 3. Like other iron(II) salts, iron(II) sulfate is a reducing agent. For example, it reduces nitric acid to nitrogen monoxide and chlorine to chloride: 6 FeSO 4 + 3 H 2 SO 4 + 2 HNO 3 → 3 Fe 2 (SO 4) 3 + 4 H 2 O + 2 NO
The finished coating is chemically stable and very adherent. It is stable up to 400 °F (204 °C); above this temperature the coating degrades due to oxidation of the base copper. To increase corrosion resistance, the surface may be oiled, lacquered, or waxed. It is also used as a pre-treatment for painting or enamelling.
Oak galls have been used in the production of ink since at least the time of the Roman Empire. From the Middle Ages to the early twentieth century, iron gall ink was the main medium used for writing in the Western world. [2] Gall nuts are a source of tannin in the production of iron gall ink. Tannins belong to a group of molecules known as ...
Tannic acid chemically converts the reddish iron oxides into bluish-black ferric tannate, a more stable material. [2] The second active ingredient is an organic solvent such as 2-butoxyethanol (ethylene glycol monobutyl ether, trade name butyl cellosolve) that acts as a wetting agent and provides a protective primer layer in conjunction with an ...