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The fertilizer grade (15.5-0-0 + 19% Ca) is popular in the greenhouse and hydroponics trades; it contains ammonium nitrate and water, as the "double salt" 5Ca(NO 3) 2 ·NH 4 NO 3 ·10H 2 O. This is called calcium ammonium nitrate and often the name calcium nitrate
The term "calcium ammonium nitrate" is applied to multiple different, but closely related formulations. One variety of calcium ammonium nitrate is made by adding powdered limestone to ammonium nitrate; [1] [2] another, fully water-soluble version, is a mixture of calcium nitrate and ammonium nitrate, which crystallizes as a hydrated double salt: [3] 5Ca(NO 3) 2 •NH 4 NO 3 •10H 2 O.
Calcium ammonium nitrate Is a blend of 20-30% limestone CaCO 3 or dolomite (Ca,Mg)CO 3 and 70-80% ammonium nitrate with 24-28 % nitrogen. Calcium nitrate with 15,5% nitrogen and 19% calcium, reportedly holding a small share of the nitrogen fertilizer market (4% in 2007). [28] The main straight phosphate fertilizers are the superphosphates:
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Fertilizers with additional macronutrients (S, Ca, Mg) may add more numbers to the N-P-K ratio to indicate the amount. The additional numbers are similarly reported in the oxide mass fraction form. For example, a Polish fertilizer labeled "NPK (Ca,S) 4-12-12 (14-29)" has an equivalent of 14% soluble calcium oxide and 29% total sulfur trioxide. [6]
The calcium nitrate mentioned before, can as said be worked up as calcium nitrate fertilizer but often it is converted into ammonium nitrate and calcium carbonate using carbon dioxide and ammonia. Ca ( NO 3 ) 2 + 2 NH 3 + CO 2 + H 2 O 2 NH 4 NO 3 + CaCO 3 {\displaystyle {\ce {Ca(NO3)2 + 2 NH3 + CO2 + H2O -> 2 NH4NO3 + CaCO3}}}