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Thus, to get current density from molar flux one needs to multiply by Faraday's constant F (Coulombs/mol). F will then cancel from the equation below. Since the valence has already been accounted for above, the charge q A of each ion in the equation above, therefore, should be interpreted as +1 or -1 depending on the polarity of the ion.
The relation between C, the counter ion concentration at the surface, and , the counter ion concentration in the external solution, is the Boltzmann factor: = where z is the charge on the ion, e is the charge of a proton, k B is the Boltzmann constant and ψ is the potential of the charged surface.
When charged particles move in electric and magnetic fields the following two laws apply: Lorentz force law: = (+),; Newton's second law of motion: = =; where F is the force applied to the ion, m is the mass of the particle, a is the acceleration, Q is the electric charge, E is the electric field, and v × B is the cross product of the ion's velocity and the magnetic flux density.
In electromagnetism, charge density is the amount of electric charge per unit length, surface area, or volume. Volume charge density (symbolized by the Greek letter ρ) is the quantity of charge per unit volume, measured in the SI system in coulombs per cubic meter (C⋅m −3), at any point in a volume.
The ion mass is expressed in units of the proton mass, = / and the ion charge in units of the elementary charge, = / (in the case of a fully ionized atom, equals to the respective atomic number). The other physical quantities used are the Boltzmann constant ( k B {\displaystyle k_{\text{B}}} ), speed of light ( c {\displaystyle c} ), and the ...
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
The Poisson–Boltzmann equation describes a model proposed independently by Louis Georges Gouy and David Leonard Chapman in 1910 and 1913, respectively. [3] In the Gouy-Chapman model, a charged solid comes into contact with an ionic solution, creating a layer of surface charges and counter-ions or double layer. [4]
In electromagnetism, current density is the amount of charge per unit time that flows through a unit area of a chosen cross section. [1] The current density vector is defined as a vector whose magnitude is the electric current per cross-sectional area at a given point in space, its direction being that of the motion of the positive charges at this point.