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H 3 PO 4 + 2 NaOH → Na 2 HPO 4 + 2 H 2 O. Industrially It is prepared in a two-step process by treating dicalcium phosphate with sodium bisulfate, which precipitates calcium sulfate: [2] CaHPO 4 + NaHSO 4 → NaH 2 PO 4 + CaSO 4. In the second step, the resulting solution of monosodium phosphate is partially neutralized: NaH 2 PO 4 + NaOH → ...
In both cases the phosphoric acid solution usually contains 23–33% P 2 O 5 (32–46% H 3 PO 4). It may be concentrated to produce commercial-or merchant-grade phosphoric acid, which contains about 54–62% P 2 O 5 (75–85% H 3 PO 4). Further removal of water yields superphosphoric acid with a P 2 O 5 concentration above 70% (corresponding to ...
When solutions with less than 18.4% NaOH are cooled, water ice crystallizes first, leaving the NaOH in solution. [18] The α form of the tetrahydrate has density 1.33 g/cm 3. It melts congruously at 7.55 °C into a liquid with 35.7% NaOH and density 1.392 g/cm 3, and therefore floats on it like ice on water
In chemistry, the mass concentration ρ i (or γ i) is defined as the mass of a constituent m i divided by the volume of the mixture V. [1]= For a pure chemical the mass concentration equals its density (mass divided by volume); thus the mass concentration of a component in a mixture can be called the density of a component in a mixture.
Dilution is the process of decreasing the concentration of a solute in a solution, usually simply by mixing with more solvent like adding more water to the solution. To dilute a solution means to add more solvent without the addition of more solute. The resulting solution is thoroughly mixed so as to ensure that all parts of the solution are ...
Pitzer equations [1] are important for the understanding of the behaviour of ions dissolved in natural waters such as rivers, lakes and sea-water. [ 2 ] [ 3 ] [ 4 ] They were first described by physical chemist Kenneth Pitzer . [ 5 ]
Any −OH groups on the phosphates in these ester molecules may lose H + ions to form anions, again depending on the pH in a solution. In the biochemistry of living organisms, there are many kinds of (mono)phosphate, diphosphate, and triphosphate compounds (essentially esters ), many of which play a significant role in metabolism such as ...
An example is the volumetric standardisation of a solution of sodium hydroxide which has been prepared to approximately 0.1 mol dm −3. It is necessary to calculate the mass of a solid acid which will react with about 20 cm 3 of this solution (for a titration using a 25 cm 3 burette ): suitable solid acids include oxalic acid dihydrate ...