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  2. Endothermic process - Wikipedia

    en.wikipedia.org/wiki/Endothermic_process

    An endothermic process is a chemical or physical process that absorbs heat from its surroundings. [1] In terms of thermodynamics, it is a thermodynamic process with an increase in the enthalpy H (or internal energy U) of the system. [2] In an endothermic process, the heat that a system absorbs is thermal energy transfer into the

  3. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".

  4. Thermochemical equation - Wikipedia

    en.wikipedia.org/wiki/Thermochemical_equation

    In thermochemistry, a thermochemical equation is a balanced chemical equation that represents the energy changes from a system to its surroundings. One such equation involves the enthalpy change, which is denoted with Δ H {\displaystyle \Delta H} In variable form, a thermochemical equation would appear similar to the following:

  5. Transition state theory - Wikipedia

    en.wikipedia.org/wiki/Transition_state_theory

    Even though the theory is widely applicable, it does have limitations. For example, when applied to each elementary step of a multi-step reaction, the theory assumes that each intermediate is long-lived enough to reach a Boltzmann distribution of energies before continuing to the next step. When the intermediates are very short-lived, TST fails ...

  6. Thermal decomposition - Wikipedia

    en.wikipedia.org/wiki/Thermal_decomposition

    The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing decomposition. If decomposition is sufficiently exothermic, a positive feedback loop is created producing thermal runaway and possibly an explosion or other chemical reaction. Thermal decomposition is a chemical reaction where heat is a ...

  7. Endotherm - Wikipedia

    en.wikipedia.org/wiki/Endotherm

    An endotherm (from Greek ἔνδον endon "within" and θέρμη thermē "heat") is an organism that maintains its body at a metabolically favorable temperature, largely by the use of heat released by its internal bodily functions instead of relying almost purely on ambient heat.

  8. Enthalpy change of solution - Wikipedia

    en.wikipedia.org/wiki/Enthalpy_change_of_solution

    The energy change can be regarded as being made up of three parts: the endothermic breaking of bonds within the solute and within the solvent, and the formation of attractions between the solute and the solvent. An ideal solution has a null enthalpy of mixing.

  9. Heat equation - Wikipedia

    en.wikipedia.org/wiki/Heat_equation

    This equation therefore describes the end result in all thermal problems in which a source is switched on (for example, an engine started in an automobile), and enough time has passed for all permanent temperature gradients to establish themselves in space, after which these spatial gradients no longer change in time (as again, with an ...