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MSDS for benzene is available at AMOCO. ... Bond energy? Bond length: 1.39 Å C-C [1] Molecular geometry: 120 °C–C–C 120° H–C–C Magnetic susceptibility?
The existence of a very long C–C bond length of up to 290 pm is claimed in a dimer of two tetracyanoethylene dianions, although this concerns a 2-electron-4-center bond. [4] [5] This type of bonding has also been observed in neutral phenalenyl dimers. The bond lengths of these so-called "pancake bonds" [6] are up to 305 pm.
English: Bond lengths and angles of benzene and different group 15 heterobenzenes (from left to right: benzene, pyridine, phosphabenzene, arsabenzene, stilbabenzene, and bismabenzene) Date 25 April 2010
The C–C bond lengths are greater than a double bond (135 pm) but shorter than a single bond (147 pm). This intermediate distance is caused by electron delocalization : the electrons for C=C bonding are distributed equally between each of the six carbon atoms.
The average length of a C–C single bond is 154 pm; that of a C=C double bond is 133 pm. In localized cyclohexatriene, the carbon–carbon bonds should be alternating 154 and 133 pm. Instead, all carbon–carbon bonds in benzene are found to be about 139 pm, a bond length intermediate between single and double bond.
para-disub. benzene 800–860 strong alkynes: any 3300 medium aldehydes: any 2720 medium 2820 C═C acyclic C═C monosub. alkenes 1645 medium 1,1-disub. alkenes 1655 medium cis-1,2-disub. alkenes 1660 medium trans-1,2-disub. alkenes 1675 medium trisub., tetrasub. alkenes 1670 weak conjugated C═C dienes 1600 strong 1650 strong with benzene ...
For example, (η 5 –cyclopentadienyl) 2 Cr (ML 4 X 2) and (η 6 –benzene) 2 Cr (ML 6) both have a LBN of 6 as compared to classical coordination numbers of 10 and 12. [3] Well known complexes such as Ferrocene and Uranocene also serve as examples where LBN and coordination number differ.
Comparison of bond lengths in simple hydrocarbons [5] Molecule Ethane: Ethylene: Acetylene: Formula C 2 H 6: C 2 H 4: C 2 H 2: Class alkane: alkene: alkyne: Structure Hybridisation of carbon sp 3: sp 2: sp C-C bond length 153.5 pm: 133.9 pm: 120.3 pm: Proportion of C-C single bond 100% 87% 78% Structure determination method microwave ...