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In physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy.
These definitions apply to all equations of state below as well. Proposed in 1873, the van der Waals equation of state was one of the first to perform markedly better than the ideal gas law. In this equation, usually is called the attraction parameter and the repulsion parameter (or the effective molecular volume). While the equation is ...
The Benedict–Webb–Rubin equation (BWR), named after Manson Benedict, G. B. Webb, and L. C. Rubin, is an equation of state used in fluid dynamics.Working at the research laboratory of the M. W. Kellogg Company, the three researchers rearranged the Beattie–Bridgeman equation of state and increased the number of experimentally determined constants to eight.
Figure A: The surface generated by the ideal gas equation. The van der Waals equation is a mathematical formula that describes the behavior of real gases. It is named after Dutch physicist Johannes Diderik van der Waals. It is an equation of state that relates the pressure, temperature, and molar volume in a fluid.
In physics, the thermal equation of state is a mathematical expression of pressure P, temperature T, and, volume V.The thermal equation of state for ideal gases is the ideal gas law, expressed as PV=nRT (where R is the gas constant and n the amount of substance), while the thermal equation of state for solids is expressed as:
Only one equation of state will not be sufficient to reconstitute the fundamental equation. All equations of state will be needed to fully characterize the thermodynamic system. Note that what is commonly called "the equation of state" is just the "mechanical" equation of state involving the Helmholtz potential and the volume:
In the thermodynamics of equilibrium, a state function, function of state, or point function for a thermodynamic system is a mathematical function relating several state variables or state quantities (that describe equilibrium states of a system) that depend only on the current equilibrium thermodynamic state of the system [1] (e.g. gas, liquid, solid, crystal, or emulsion), not the path which ...
"Equation of State Calculations by Fast Computing Machines" is a scholarly article published by Nicholas Metropolis, Arianna W. Rosenbluth, Marshall N. Rosenbluth, Augusta H. Teller, and Edward Teller in the Journal of Chemical Physics in 1953. [1]