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  2. Heterogeneous water oxidation - Wikipedia

    en.wikipedia.org/wiki/Heterogeneous_Water_Oxidation

    2H 2 O → O 2 + 4H + + 4e − Oxidation (generation of dioxygen) 4H + + 4e − → 2H 2 Reduction (generation of dihydrogen) 2H 2 O → 2H 2 + O 2 Total Reaction Of the two half reactions, the oxidation step is the most demanding because it requires the coupling of 4 electron and proton transfers and the formation of an oxygen-oxygen bond.

  3. Oxygen reduction reaction - Wikipedia

    en.wikipedia.org/wiki/Oxygen_reduction_reaction

    The 4e − pathway reaction is the cathode reaction in fuel cell especially in proton-exchange membrane fuel cells, alkaline fuel cell and solid oxide fuel cell. While the 2e − pathway reaction is often the side reaction of 4e- pathway or can be used in synthesis of H 2 O 2 .

  4. Table of standard reduction potentials for half-reactions ...

    en.wikipedia.org/wiki/Table_of_standard...

    CH 3 COOH + 2H + + 2e − → CH 3 CHO + H 2 O: −0.58 Many carboxylic acid: aldehyde redox reactions have a potential near this value 2 H + + 2 e − → H 2: −0.41 Non-zero value for the hydrogen potential because at pH = 7, [H +] = 10 −7 M and not 1 M as in the standard hydrogen electrode (SHE), and that: E red = -0.059 V × 7 = -0.41 V ...

  5. Dioxygen in biological reactions - Wikipedia

    en.wikipedia.org/wiki/Dioxygen_in_biological...

    Photolytic oxygen evolution during photosynthesis occurs via the light-dependent oxidation of water to molecular oxygen and can be written as the following simplified chemical reaction: 2H 2 O → 4e − + 4H + + O 2

  6. Standard electrode potential (data page) - Wikipedia

    en.wikipedia.org/wiki/Standard_electrode...

    2 (s) + 4 H + + e −: ⇌ Mn 3+ + 2 H 2 O: 0.95 1 N NO − 3 (aq) + 4 H + + 3 e −: ⇌ NO(g) + 2 H 2 O (l) 0.958 3 [7] Au [AuBr 2] − + e −: ⇌ Au(s) + 2 Br −: 0.96 1 Fe Fe 3 O 4 (s) + 8 H + + 2 e −: ⇌ 3 Fe 2+ + 4 H 2 O: 0.98 2 [18]: p.100 Xe [HXeO 6] 3− + 2 H 2 O + 2 e −: ⇌ [HXeO 4] − + 4 OH −: 0.99 2 [6]: 792 [26] N ...

  7. Oxygen-evolving complex - Wikipedia

    en.wikipedia.org/wiki/Oxygen-evolving_complex

    Photons trapped by photosystem II move the system from state S 0 to S 1 to S 2 to S 3 and finally to S 4. S 4 reacts with water producing free oxygen: 2 H 2 O → O 2 + 4 H + + 4 e −. This conversion resets the catalyst to the S 0 state. The active site of the OEC consists of a cluster of manganese and calcium with the formula Mn 4 Ca 1 O x ...

  8. Oxygen evolution - Wikipedia

    en.wikipedia.org/wiki/Oxygen_evolution

    2h 2 o 4e − + 4h + + o 2 The protons are released into the thylakoid lumen , thus contributing to the generation of a proton gradient across the thylakoid membrane. This proton gradient is the driving force for adenosine triphosphate (ATP) synthesis via photophosphorylation and the coupling of the absorption of light energy and the oxidation ...

  9. Standard electrode potential - Wikipedia

    en.wikipedia.org/wiki/Standard_electrode_potential

    Bipolar electrochemistry scheme. In electrochemistry, standard electrode potential, or , is a measure of the reducing power of any element or compound.The IUPAC "Gold Book" defines it as; "the value of the standard emf (electromotive force) of a cell in which molecular hydrogen under standard pressure is oxidized to solvated protons at the left-hand electrode".