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  2. Swarts fluorination - Wikipedia

    en.wikipedia.org/wiki/Swarts_fluorination

    Heating the mixture of the metal fluoride and the haloalkane (chlorine and bromine are replaced readily) yields the desired fluoroalkane. In some particularly reactive cases, heating is unnecessary; shaking or stirring the reaction mixture is sufficient. This reaction has a good yield.

  3. Hydrohalogenation - Wikipedia

    en.wikipedia.org/wiki/Hydrohalogenation

    A hydrohalogenation reaction is the electrophilic addition of hydrogen halides like hydrogen chloride or hydrogen bromide to alkenes to yield the corresponding haloalkanes. [ 1 ] [ 2 ] [ 3 ] If the two carbon atoms at the double bond are linked to a different number of hydrogen atoms, the halogen is found preferentially at the carbon with fewer ...

  4. Free-radical halogenation - Wikipedia

    en.wikipedia.org/wiki/Free-radical_halogenation

    The relative rates at which different halogens react vary considerably: [citation needed] fluorine (108) > chlorine (1) > bromine (7 × 10 −11) > iodine (2 × 10 −22).. Radical fluorination with the pure element is difficult to control and highly exothermic; care must be taken to prevent an explosion or a runaway reaction.

  5. Haloalkane - Wikipedia

    en.wikipedia.org/wiki/Haloalkane

    Only haloalkanes that contain chlorine, bromine, and iodine are a threat to the ozone layer, but fluorinated volatile haloalkanes in theory may have activity as greenhouse gases. Methyl iodide , a naturally occurring substance, however, does not have ozone-depleting properties and the United States Environmental Protection Agency has designated ...

  6. Halomethane - Wikipedia

    en.wikipedia.org/wiki/Halomethane

    Reaction of methane with hypochlorous acid, ... the third is the chlorine atoms, and the fourth is the number of bromine atoms. ... Two groups of haloalkanes, ...

  7. Metal–halogen exchange - Wikipedia

    en.wikipedia.org/wiki/Metal–halogen_exchange

    An intramolecular S N 2 reaction by the anion forms the cyclic backbone of morphine. [14] Synthesis of morphine using lithium–halogen exchange. Lithium–halogen exchange is a crucial part of Parham cyclization. [15] In this reaction, an aryl halide (usually iodide or bromide) exchanges with organolithium to form a lithiated arene species.

  8. Halocarbon - Wikipedia

    en.wikipedia.org/wiki/Halocarbon

    Halocarbon compounds are chemical compounds in which one or more carbon atoms are linked by covalent bonds with one or more halogen atoms (fluorine, chlorine, bromine or iodine – group 17) resulting in the formation of organofluorine compounds, organochlorine compounds, organobromine compounds, and organoiodine compounds.

  9. Haloform reaction - Wikipedia

    en.wikipedia.org/wiki/Haloform_reaction

    In chemistry, the haloform reaction (also referred to as the Lieben haloform reaction) is a chemical reaction in which a haloform (CHX 3, where X is a halogen) is produced by the exhaustive halogenation of an acetyl group (R−C(=O)CH 3, where R can be either a hydrogen atom, an alkyl or an aryl group), in the presence of a base.