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  2. Quantum number - Wikipedia

    en.wikipedia.org/wiki/Quantum_number

    A quantum number beginning in n = 3,ℓ = 0, describes an electron in the s orbital of the third electron shell of an atom. In chemistry, this quantum number is very important, since it specifies the shape of an atomic orbital and strongly influences chemical bonds and bond angles. The azimuthal quantum number can also denote the number of ...

  3. Pauli exclusion principle - Wikipedia

    en.wikipedia.org/wiki/Pauli_exclusion_principle

    In the case of electrons in atoms, the exclusion principle can be stated as follows: in a poly-electron atom it is impossible for any two electrons to have the same two values of all four of their quantum numbers, which are: n, the principal quantum number; ℓ, the azimuthal quantum number; m ℓ, the magnetic quantum number; and m s, the spin ...

  4. Principal quantum number - Wikipedia

    en.wikipedia.org/wiki/Principal_quantum_number

    The four quantum numbers n, ℓ, m, and s specify the complete and unique quantum state of a single electron in an atom, called its wave function or orbital. Two electrons belonging to the same atom cannot have the same values for all four quantum numbers, due to the Pauli exclusion principle .

  5. Azimuthal quantum number - Wikipedia

    en.wikipedia.org/wiki/Azimuthal_quantum_number

    The principal quantum number (n) is shown at the right of each row. In quantum mechanics, the azimuthal quantum number ℓ is a quantum number for an atomic orbital that determines its orbital angular momentum and describes aspects of the angular shape of the orbital.

  6. Category:Quantum numbers - Wikipedia

    en.wikipedia.org/wiki/Category:Quantum_numbers

    Download as PDF; Printable version; In other projects Wikidata item; Appearance. move to sidebar hide. Help. Pages in category "Quantum numbers" The following 8 pages ...

  7. Molecular Hamiltonian - Wikipedia

    en.wikipedia.org/wiki/Molecular_Hamiltonian

    From it are missing a number of small terms, most of which are due to electronic and nuclear spin. Although it is generally assumed that the solution of the time-independent Schrödinger equation associated with the Coulomb Hamiltonian will predict most properties of the molecule, including its shape (three-dimensional structure), calculations ...

  8. Atoms in molecules - Wikipedia

    en.wikipedia.org/wiki/Atoms_in_molecules

    In quantum chemistry, the quantum theory of atoms in molecules (QTAIM), sometimes referred to as atoms in molecules (AIM), is a model of molecular and condensed matter electronic systems (such as crystals) in which the principal objects of molecular structure - atoms and bonds - are natural expressions of a system's observable electron density distribution function.

  9. Degenerate energy levels - Wikipedia

    en.wikipedia.org/wiki/Degenerate_energy_levels

    The quantum numbers corresponding to these operators are , , (always 1/2 for an electron) and respectively. The energy levels in the hydrogen atom depend only on the principal quantum number n . For a given n , all the states corresponding to ℓ = 0 , … , n − 1 {\displaystyle \ell =0,\ldots ,n-1} have the same energy and are degenerate.