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In 1803 John Dalton proposed to use the (still unknown) atomic mass of the lightest atom, hydrogen, as the natural unit of atomic mass. This was the basis of the atomic weight scale. [12] For technical reasons, in 1898, chemist Wilhelm Ostwald and others proposed to redefine the unit of atomic mass as 1 / 16 the mass of an oxygen atom. [13]
Alternately, the atomic mass of a carbon-12 atom may be expressed in any other mass units: for example, the atomic mass of a carbon-12 atom is 1.992 646 882 70 (62) × 10 −26 kg. As is the case for the related atomic mass when expressed in daltons , the relative isotopic mass numbers of nuclides other than carbon-12 are not whole numbers, but ...
The unified atomic mass unit (symbol: u) is equivalent to the dalton. One dalton is approximately the mass of one a single proton or neutron. [2] The unified atomic mass unit has a value of 1.660 538 921 (73) × 10 −27 kg. [3] The amu without the "unified" prefix is an obsolete unit based on oxygen, which was replaced in 1961.
In the context of atomic physics, using the atomic units system can be a convenient shortcut, eliminating symbols and numbers and reducing the order of magnitude of most numbers involved. For example, the Hamiltonian operator in the Schrödinger equation for the helium atom with standard quantities, such as when using SI units, is [2]
It can be converted into a measure of mass (with dimension M) by multiplying it with the dalton, also known as the atomic mass constant. Among various variants of the notion of atomic weight (A r, also known as relative atomic mass) used by scientists, the standard atomic weight (A r °) is the most common and practical.
For example, 50 g of zinc will react with oxygen to produce 62.24 g of zinc oxide, implying that the zinc has reacted with 12.24 g of oxygen (from the Law of conservation of mass): the equivalent weight of zinc is the mass which will react with eight grams of oxygen, hence 50 g × 8 g/12.24 g = 32.7 g.
Oxygen constitutes 49.2% of the Earth's crust by mass [69] as part of oxide compounds such as silicon dioxide and is the most abundant element by mass in the Earth's crust. It is also the major component of the world's oceans (88.8% by mass). [ 19 ]
The difference of the actual isotopic mass minus the mass number of an atom is known as the mass excess, [8] which for 35 Cl is –0.03115. Mass excess should not be confused with mass defect which is the difference between the mass of an atom and its constituent particles (namely protons, neutrons and electrons). There are two reasons for mass ...