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Protactinium-233 occurs as a result of the decay of thorium-233 as part of the chain of events necessary to produce uranium-233 by neutron irradiation of thorium-232. It is an undesired intermediate product in thorium-based nuclear reactors , and is therefore removed from the active zone of the reactor during the breeding process.
Uranium-233 (233 U or U-233) is a fissile isotope of uranium that is bred from thorium-232 as part of the thorium fuel cycle. Uranium-233 was investigated for use in nuclear weapons and as a reactor fuel. [2] It has been used successfully in experimental nuclear reactors and has been proposed for much wider use as a nuclear fuel.
Protactinium-233 is also part of the thorium fuel cycle. It is an intermediate beta decay product between thorium-233 (produced from natural thorium-232 by neutron capture) and uranium-233 (the fissile fuel of the thorium cycle). Some thorium-cycle reactor designs try to protect Pa-233 from further neutron capture producing Pa-234 and U-234 ...
and 233 U. [17] On a closed cycle, 233 U and 231 Pa can be reprocessed. 231 Pa is also considered an excellent burnable poison absorber in light water reactors. [23] Another challenge associated with the thorium fuel cycle is the comparatively long interval over which 232 Th breeds to 233 U. The half-life of 233 Pa
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Protactinyl nitrate, protactinium(V) oxynitrate, or erroneously known as protactinium nitrate, is a radioactive chemical compound with the formula PaO(NO 3) 3 ·xH 2 O (1.5 ≤ x ≤ 4). It is a white solid that readily hydrolyzes to protactinium(V) oxide in moist air. This compound is a common commercial source of protactinium. [2]
In the thorium cycle, thorium-232 breeds by converting first to protactinium-233, which then decays to uranium-233. If the protactinium remains in the reactor, small amounts of uranium-232 are also produced, which has the strong gamma emitter thallium-208 in its decay chain. Similar to uranium-fueled designs, the longer the fuel and fertile ...
Uranium-232 (232 U) is an isotope of uranium.It has a half-life of around 69 years and is a side product in the thorium cycle.It has been cited as an obstacle to nuclear proliferation using 233 U as the fissile material, because the intense gamma radiation emitted by 208 Tl (a daughter of 232 U, produced relatively quickly) makes the 233 U contaminated with it more difficult to handle.