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VO 2+, often in an ionic pairing with sodium (NaH 2 VO 4), is the second most abundant transition metal in seawater, with its concentration only being exceeded by molybdenum. [4] In the ocean the average concentration is 30 nM. Some mineral water springs also contain the ion in high concentrations.
From left: [V(H 2 O) 6] 2+ (lilac), [V(H 2 O) 6] 3+ (green), [VO(H 2 O) 5] 2+ (blue) and [VO(H 2 O) 5] 3+ (yellow).. Vanadium compounds are compounds formed by the element vanadium (V). The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5, whereas the chemistry of the other group 5 elements, niobium and tantalum, are somewhat more limited to ...
V 2 O 5 + SO 2 → 2 VO 2 + SO 3. The catalyst is regenerated by oxidation with air: 4 VO 2 + O 2 → 2 V 2 O 5. Similar oxidations are used in the production of maleic anhydride: C 4 H 10 + 3.5 O 2 → C 4 H 2 O 3 + 4 H 2 O. Phthalic anhydride and several other bulk organic compounds are produced similarly.
As pH rises the chromate ion becomes ever more predominant, until it is the only species in solutions with pH > 6.75. At pH < pK 1 the hydrogen chromate ion, HCrO − 4 is predominant in dilute solution. The dichromate ion, Cr 2 O 2− 7, is predominant in more concentrated solutions, except at high pH.
The V=O bond distance is 160 pm, about 50 pm shorter than the V–OH 2 bonds. In solution, the sulfate ion dissociates rapidly. Being widely available, vanadyl sulfate is a common precursor to other vanadyl derivatives, such as vanadyl acetylacetonate: [7] [V(O)(H 2 O) 4]SO 4 + 2 C 5 H 8 O 2 + Na 2 CO 3 → [V(O)(C 5 H 7 O 2) 2] + Na 2 SO 4 + 5 ...
Vanadium(IV) oxide or vanadium dioxide is an inorganic compound with the formula VO 2.It is a dark blue solid. Vanadium(IV) dioxide is amphoteric, dissolving in non-oxidising acids to give the blue vanadyl ion, [VO] 2+ and in alkali to give the brown [V 4 O 9] 2− ion, or at high pH [VO 4] 4−. [4]
The complexes [V(CN) 6] 3− and [V 2 Cl 9] 3− are referred to as hexacyanovanadate(III) and nonachlorodivanadate(III), respectively. A simple vanadate ion is the tetrahedral orthovanadate anion, VO 3− 4 (which is also called vanadate(V)), which is present in e.g. sodium orthovanadate and in solutions of V 2 O 5 in strong base (pH > 13 [1]).
2) is formed when metallic sodium is burned in oxygen. Each oxygen atom in its peroxide ion may have a full octet of 4 pairs of electrons. [6] Superoxides are a class of compounds that are very similar to peroxides, but with just one unpaired electron for each pair of oxygen atoms (O − 2). [6]