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Atomic oxygen, denoted O or O 1, is very reactive, as the individual atoms of oxygen tend to quickly bond with nearby molecules. Its lowest-energy electronic state is a spin triplet, designated by the term symbol 3 P. On Earth's surface, it exists naturally for a very short time.
With ozone concentrations in the order of 10 −6-10 −5 relative to molecular oxygen, ozone photodissociation becomes the dominant photodissociation reaction, and most of the stratosphere heat is generated through this procsees, with highest heat generation rate per molecule at the upper limit of the stratosphere (stratopause), where ozone ...
The excess kinetic energy heats the stratosphere when the O atoms and the molecular oxygen fly apart and collide with other molecules. This conversion of UV light into kinetic energy warms the stratosphere. The oxygen atoms produced in the photolysis of ozone then react back with other oxygen molecule as in the previous step to form more ozone.
[1] [2] Ozone is also an important constituent of the stratosphere, where the ozone layer (2 to 8 parts per million ozone) exists which is located between 10 and 50 kilometers above the Earth's surface. [3] The troposphere extends from the ground up to a variable height of approximately 14 kilometers above sea level.
Like ordinary ozone (O 3), it would have three oxygen atoms. It would differ from ordinary ozone in how those three oxygen atoms are arranged. In ordinary ozone, the atoms are arranged in a bent line; in cyclic ozone, they would form an equilateral triangle. Some of the properties of cyclic ozone have been predicted theoretically.
The bond can be variously described based on level of theory, but is reasonably and simply described as a covalent double bond that results from the filling of molecular orbitals formed from the atomic orbitals of the individual oxygen atoms, the filling of which results in a bond order of two.
Ozone cycle illustrated over image by NASA astronaut Scott Kelly. Ozone is a ubiquitous yet highly reactive molecule in the atmosphere. Such a highly reactive oxidizer would normally be dangerous to life but ozone's concentration at sea level is usually not high enough to be toxic.
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