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Vanadium(V) oxide serves the crucial purpose of catalysing the mildly exothermic oxidation of sulfur dioxide to sulfur trioxide by air in the contact process: 2 SO 2 + O 2 ⇌ 2 SO 3 The discovery of this simple reaction, for which V 2 O 5 is the most effective catalyst, allowed sulfuric acid to become the cheap commodity chemical it is today.
The contact process is a method of producing sulfuric acid in the high concentrations needed for industrial processes. Platinum was originally used as the catalyst for this reaction; however, because it is susceptible to reacting with arsenic impurities in the sulfur feedstock, vanadium(V) oxide (V 2 O 5) has since been preferred.
Vanadium(V) oxide is a catalyst in the contact process for producing sulfuric acid. Vanadium compounds are used extensively as catalysts; [83] Vanadium pentoxide V 2 O 5, is used as a catalyst in manufacturing sulfuric acid by the contact process [84] In this process sulfur dioxide (SO 2) is oxidized to the trioxide (SO
Process Catalyst Product Application sulfur dioxide: contact process: vanadium pentoxide (heterogeneous) sulfuric acid: fertilizer production ammonia: Ostwald process: platinum (heterogeneous) nitric acid: basic chemicals, TNT: hydrogen sulfide: Claus process: vanadium pentoxide (heterogeneous) sulfur: remediation of byproduct of oil refinery ...
If the catalyst and reaction conditions are indicative of low effectiveness, selective poisoning may be observed, where poisoning of only a small fraction of the catalyst's surface gives a disproportionately large drop in activity. [4] If η is the effectiveness factor of the poisoned surface and h p is the Thiele modulus for the poisoned case:
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The heterogeneous process ultimately failed due to catalyst inactivation and was replaced by the water-based homogeneous system for which a pilot plant was operational in 1958. Problems with the aggressive catalyst solution were solved by adopting titanium (newly available for industrial use) as construction material for reactors and pumps ...
Here’s an important heads-up for parents who are trying to ease their babies through the teething stage: one of the tools you might be using could be unsafe.