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Furthermore, theories have been put forward to take into account the effects of vibronic coupling on electron transfer, in particular, the PKS theory of electron transfer. [10] In proteins, ET rates are governed by the bond structures: the electrons, in effect, tunnel through the bonds comprising the chain structure of the proteins. [11]
The main theory describing the rates of outer sphere electron transfer was developed by Rudolph A. Marcus in the 1950s, for which he was awarded the Nobel Prize in Chemistry in 1992. [2] A major aspect of Marcus theory is the dependence of the electron transfer rate on the thermodynamic driving force (difference in the redox potentials of the ...
In theoretical chemistry, Marcus theory is a theory originally developed by Rudolph A. Marcus, starting in 1956, to explain the rates of electron transfer reactions – the rate at which an electron can move or jump from one chemical species (called the electron donor) to another (called the electron acceptor). [1]
Arrow pushing or electron pushing is a technique used to describe the progression of organic chemistry reaction mechanisms. [1] It was first developed by Sir Robert Robinson.In using arrow pushing, "curved arrows" or "curly arrows" are drawn on the structural formulae of reactants in a chemical equation to show the reaction mechanism.
Solvated electrons are involved in the reaction of alkali metals with water, even though the solvated electron has only a fleeting existence. [10] Below pH = 9.6 the hydrated electron reacts with the hydronium ion giving atomic hydrogen, which in turn can react with the hydrated electron giving hydroxide ion and usual molecular hydrogen H 2. [11]
Pictorial description of how an electron beam may interact with a sample with nucleus N, and electron cloud of electron shells K,L,M. Showing transmitted electrons and elastic/inelastically scattered electrons. SE is a Secondary Electron ejected by the beam electron, emitting a characteristic photon (X-Ray) γ.
A Proton-coupled electron transfer (PCET) is a chemical reaction that involves the transfer of electrons and protons from one atom to another. The term was originally coined for single proton, single electron processes that are concerted, [ 1 ] but the definition has relaxed to include many related processes.
Electron capture is always an alternative decay mode for radioactive isotopes that do have sufficient energy to decay by positron emission. Electron capture is sometimes included as a type of beta decay , [ 1 ] because the basic nuclear process, mediated by the weak force, is the same.