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In this situation, there is a distinction between "optical band gap" and "electronic band gap" (or "transport gap"). The optical bandgap is the threshold for photons to be absorbed, while the transport gap is the threshold for creating an electron–hole pair that is not bound together. The optical bandgap is at lower energy than the transport gap.
To understand how band structure changes relative to the Fermi level in real space, a band structure plot is often first simplified in the form of a band diagram. In a band diagram the vertical axis is energy while the horizontal axis represents real space. Horizontal lines represent energy levels, while blocks represent energy bands.
In the simplest description of a semiconductor, a single parameter is used to quantify the onset of optical absorption: the band gap, . In this description, semiconductors are described as being able to absorb photons above E G {\displaystyle E_{G}} , but are transparent to photons below E G {\displaystyle E_{G}} . [ 2 ]
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In semiconductors, the band gap of a semiconductor can be of two basic types, a direct band gap or an indirect band gap. The minimal-energy state in the conduction band and the maximal-energy state in the valence band are each characterized by a certain crystal momentum (k-vector) in the Brillouin zone. If the k-vectors are different, the ...
The zero-phonon line is an optical analogy to the Mössbauer lines, which originate in the recoil-free emission or absorption of gamma rays from the nuclei of atoms bound in a solid matrix. In the case of the optical zero-phonon line, the position of the chromophore is the physical parameter that may be perturbed, whereas in the gamma ...
The p–n junction in any direct band gap material emits light when electric current flows through it. This is electroluminescence. Electrons cross from the n-region and recombine with the holes existing in the p-region. Free electrons are in the conduction band of energy levels, while holes are in the valence energy band. Thus the energy level ...
Band diagram for Schottky barrier at equilibrium Band diagram for semiconductor heterojunction at equilibrium. In solid-state physics of semiconductors, a band diagram is a diagram plotting various key electron energy levels (Fermi level and nearby energy band edges) as a function of some spatial dimension, which is often denoted x. [1]