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In physics, a redshift is an increase in the wavelength, and corresponding decrease in the frequency and photon energy, of electromagnetic radiation (such as light).The opposite change, a decrease in wavelength and increase in frequency and energy, is known as a blueshift, or negative redshift.
The Stokes shift is primarily the result of two phenomena: vibrational relaxation or dissipation and solvent reorganization. A fluorophore is a part of a molecule with a dipole moment that exhibits fluorescence. When a fluorophore enters an excited state, its dipole moment changes, but surrounding solvent molecules cannot adjust so quickly.
In physics and general relativity, gravitational redshift (known as Einstein shift in older literature) [1] [2] is the phenomenon that electromagnetic waves or photons travelling out of a gravitational well lose energy. This loss of energy corresponds to a decrease in the wave frequency and increase in the wavelength, known more generally as a ...
In spectroscopy, bathochromic shift (from Greek βαθύς (bathys) 'deep' and χρῶμα (chrōma) 'color'; hence less common alternate spelling "bathychromic") is a change of spectral band position in the absorption, reflectance, transmittance, or emission spectrum of a molecule to a longer wavelength (lower frequency). [1]
Example of normal Stokes emission through fluorescence (left, red) and anti-Stokes emission (right, blue) through sensitized triplet-triplet annihilation based photon upconversion, samples excited with green light. Upconversion fluorescence. Optical fiber that contains infrared light shines with a blue color in the dark
Rubies, emeralds, and diamonds exhibit red fluorescence under long-wave UV, blue and sometimes green light; diamonds also emit light under X-ray radiation. Fluorescence in minerals is caused by a wide range of activators. In some cases, the concentration of the activator must be restricted to below a certain level, to prevent quenching of the ...
Because the blue color in the visible spectrum has a shorter wavelength than most other colors, this effect is also commonly called a blue shift. [1] It should not be confused with a bathochromic shift, which is the opposite process – the molecule's spectra are changed to a longer wavelength (lower frequency).
Rather than attempt direct measurement of the TDE, Ives and Stilwell (1938) used a concave mirror that allowed them to simultaneously observe a nearly longitudinal direct beam (blue) and its reflected image (red). Spectroscopically, three lines would be observed: An undisplaced emission line, and blueshifted and redshifted lines.