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The hysteresis of a hydrogel refers to the phenomenon where there is a delay in the deformation and recovery of a hydrogel when it is subjected to mechanical stress and relieved of that stress. This occurs because the polymer chains within a hydrogel rearrange, and the water molecules are displaced, and energy is stored as it deforms in ...
Self-healing hydrogels are a specialized type of polymer hydrogel.A hydrogel is a macromolecular polymer gel constructed of a network of crosslinked polymer chains. Hydrogels are synthesized from hydrophilic monomers by either chain or step growth, along with a functional crosslinker to promote network formation.
Poly(2-hydroxyethyl methacrylate) (pHEMA) is a polymer that forms a hydrogel in water. Poly (hydroxyethyl methacrylate) (PHEMA) hydrogel for intraocular lens (IOL) materials was synthesized by solution polymerization using 2-hydroxyethyl methacrylate as raw material, ammonium persulfate and sodium pyrosulfite (APS/SMBS) as catalyst, and triethyleneglycol dimethacrylate (TEGDMA) as cross ...
A SAP's ability to absorb water depends on the ionic concentration of the aqueous solution. In deionized and distilled water, a SAP may absorb 300 times its weight [4] (from 30 to 60 times its own volume) and can become up to 99.9% liquid, and when put into a 0.9% saline solution the absorbency drops to approximately 50 times its weight.
SMPs have demonstrated recoverable strains of above 800%. [7] Two important quantities that are used to describe shape-memory effects are the strain recovery rate (R r) and strain fixity rate (R f). The strain recovery rate describes the ability of the material to memorize its permanent shape, while the strain fixity rate describes the ability ...
The primary, and likely most widely employed, strain-energy function formulation is the Mooney-Rivlin model, which reduces to the widely known neo-Hookean model. The strain energy density function for an incompressible Mooney—Rivlin material is = + (); =
Specifically, hydrogels can be designed to release drugs or other agents in response to physical characteristics of the environment like temperature and pH. [12] The responsiveness of hydrogels is a result of their molecular structure and polymer networks. [12] Hydrogel nanoparticles have a promising future in the drug delivery field.
Schematic representation of the different stages and routes of the sol–gel technology. In this chemical procedure, a "sol" (a colloidal solution) is formed that then gradually evolves towards the formation of a gel-like diphasic system containing both a liquid phase and solid phase whose morphologies range from discrete particles to continuous polymer networks.