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  2. Free-radical halogenation - Wikipedia

    en.wikipedia.org/wiki/Free-radical_halogenation

    Two free radicals (chlorine and chlorine, chlorine and methyl, or methyl and methyl) combine: Methane chlorination: termination The last possibility generates in an impurity in the final mixture (notably, an organic molecule with a longer carbon chain than the reactants). The net reaction is: Methane chlorination overall reaction

  3. Photochlorination - Wikipedia

    en.wikipedia.org/wiki/Photochlorination

    Photochlorination is a chlorination reaction that is initiated by light. Usually a C-H bond is converted to a C-Cl bond. Photochlorination is carried out on an industrial scale. The process is exothermic and proceeds as a chain reaction initiated by the homolytic cleavage of molecular chlorine into chlorine radicals by ultraviolet radiation ...

  4. Peters four-step chemistry - Wikipedia

    en.wikipedia.org/wiki/Peters_four-step_chemistry

    The third reaction, known as radical consumption layer, where most of the heat is released, and the first reaction, also known as fuel consumption layer, occur in a narrow region at the flame. The fourth reaction is the hydrogen oxidation layer, whose thickness is much larger than the former two layers.

  5. Molecular model - Wikipedia

    en.wikipedia.org/wiki/Molecular_model

    The term, "molecular model" refer to systems that contain one or more explicit atoms (although solvent atoms may be represented implicitly) and where nuclear structure is neglected. The electronic structure is often also omitted unless it is necessary in illustrating the function of the molecule being modeled.

  6. Dichloromethane - Wikipedia

    en.wikipedia.org/wiki/Dichloromethane

    DCM is produced by treating either chloromethane or methane with chlorine gas at 400–500 °C. At these temperatures, both methane and chloromethane undergo a series of reactions producing progressively more chlorinated products. In this way, an estimated 400,000 tons were produced in the US, Europe, and Japan in 1993. [12] CH 4 + Cl 2 → CH ...

  7. Trihalomethane - Wikipedia

    en.wikipedia.org/wiki/Trihalomethane

    In chemistry, trihalomethanes (THMs) are chemical compounds in which three of the four hydrogen atoms of methane (CH 4) are replaced by halogen atoms. Trihalomethanes with all the same halogen atoms are called haloforms. Many trihalomethanes find uses in industry as solvents or refrigerants.

  8. Trichlorofluoromethane - Wikipedia

    en.wikipedia.org/wiki/Trichlorofluoromethane

    The reaction can also be carried out in the presence of antimony(III) chloride or antimony(V) chloride: [8] CCl 4 + HF → CCl 3 F + CF 4 + CCl 2 F 2. Trichlorofluoromethane is also formed as one of the byproducts when graphite reacts with chlorine and hydrogen fluoride at 500 °C. [8]

  9. Bond energy - Wikipedia

    en.wikipedia.org/wiki/Bond_energy

    For example, the carbon–hydrogen bond energy in methane BE (C–H) is the enthalpy change (∆H) of breaking one molecule of methane into a carbon atom and four hydrogen radicals, divided by four. The exact value for a certain pair of bonded elements varies somewhat depending on the specific molecule, so tabulated bond energies are generally ...