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Equation of state. In physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. [1] Most modern equations of state are formulated in the Helmholtz free energy.
In physics, the thermal equation of state is a mathematical expression of pressure P, temperature T, and, volume V.The thermal equation of state for ideal gases is the ideal gas law, expressed as PV=nRT (where R is the gas constant and n the amount of substance), while the thermal equation of state for solids is expressed as:
The two most significant results of the Drude model are an electronic equation of motion, = (+ ) , and a linear relationship between current density J and electric field E, =. Here t is the time, p is the average momentum per electron and q, n, m , and τ are respectively the electron charge, number density, mass, and mean free time between ...
In thermodynamics and solid-state physics, the Debye model is a method developed by Peter Debye in 1912 to estimate phonon contribution to the specific heat (heat capacity) in a solid. [2] It treats the vibrations of the atomic lattice (heat) as phonons in a box in contrast to the Einstein photoelectron model , which treats the solid as many ...
The first constitutive equation (constitutive law) was developed by Robert Hooke and is known as Hooke's law.It deals with the case of linear elastic materials.Following this discovery, this type of equation, often called a "stress-strain relation" in this example, but also called a "constitutive assumption" or an "equation of state" was commonly used.
In physics, Planck's law (also Planck radiation law[ 1 ]: 1305) describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature T, when there is no net flow of matter or energy between the body and its environment. [ 2 ]
The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them (both of which depend on the specific substance). As a result the equation is able to model the phase ...
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...