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Thermal expansion generally decreases with increasing bond energy, which also has an effect on the melting point of solids, so high melting point materials are more likely to have lower thermal expansion. In general, liquids expand slightly more than solids. The thermal expansion of glasses is slightly higher compared to that of crystals. [5]
When the cause of the convection is unspecified, convection due to the effects of thermal expansion and buoyancy can be assumed. Convection may also take place in soft solids or mixtures where particles can flow. Thermal image of a newly lit Ghillie kettle. The plume of hot air resulting from the convection current is visible.
The molecules in a drop of food coloring added to water will eventually disperse throughout the entire medium, where the effects of molecular diffusion are more evident. However, stirring the mixture with a spoon will create turbulent flows in the water that accelerate the process of dispersion through convection-dominated dispersion.
However, when the vibrational amplitudes are large, for example at high temperatures, anharmonicity becomes important. An example of the effects of anharmonicity is the thermal expansion of solids, which is usually studied within the quasi-harmonic approximation. Studying vibrating anharmonic systems using quantum mechanics is a computationally ...
In thermodynamics and fluid mechanics, the compressibility (also known as the coefficient of compressibility [1] or, if the temperature is held constant, the isothermal compressibility [2]) is a measure of the instantaneous relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.
Negative thermal expansion (NTE) is an unusual physicochemical process in which some materials contract upon heating, rather than expand as most other materials do. The most well-known material with NTE is water at 0 to 3.98 °C. Also, the density of solid water (ice) is lower than the density of liquid water at standard pressure.
The method of expansion discussed in this article, in which a gas or liquid at pressure P 1 flows into a region of lower pressure P 2 without significant change in kinetic energy, is called the Joule–Thomson expansion. The expansion is inherently irreversible. During this expansion, enthalpy remains unchanged (see proof below). Unlike a free ...
In general, compressibility is defined as the relative volume change of a fluid or solid as a response to a pressure, and may be determined for substances in any phase. Similarly, thermal expansion is the tendency of matter to change in volume in response to a change in temperature.