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The Dieckmann condensation, where a molecule with two ester groups reacts intramolecularly, forming a cyclic β-keto ester. In this case, the ring formed must not be strained, usually a 5- or 6-membered chain or ring. Retro-Claisen condensation is the reverse of the title reaction, i.e., the base-induced cleavage of 2-ketoesters
The systematic name of this enzyme class is (3S)-citryl-CoA oxaloacetate-lyase (acetyl-CoA-forming). This enzyme is also called (3 S )-citryl-CoA oxaloacetate-lyase . This enzyme participates in citrate cycle (tca cycle) .
Thiolases are a family of evolutionarily related enzymes.Two different types of thiolase [4] [5] [6] are found both in eukaryotes and in prokaryotes: acetoacetyl-CoA thiolase (EC 2.3.1.9) and 3-ketoacyl-CoA thiolase (EC 2.3.1.16). 3-ketoacyl-CoA thiolase (also called thiolase I) has a broad chain-length specificity for its substrates and is involved in degradative pathways such as fatty acid ...
The reaction is known as the Claisen reaction and was described by Claisen for the first time in 1890. Discovered the thermally induced rearrangement of allyl phenyl ether in 1912. He details its reaction mechanism in his last scientific publication (1925). In his honor, the reaction has been named the Claisen rearrangement.
Claisen condensation; Claisen rearrangement; Claisen–Schmidt condensation; Clemmensen reduction; Collins reagent; Combes quinoline synthesis; Conia reaction; Conrad–Limpach synthesis; Cook–Heilbron thiazole synthesis; Cope elimination; Cope rearrangement [24] Corey reagent; Corey–Bakshi–Shibata reduction; Corey–Fuchs reaction; Corey ...
The role of the ACS enzyme is to combine acetate and Coenzyme A to form acetyl-CoA, however its significance is much larger. The most well known function of the product from this enzymatic reaction is the use of acetyl-CoA in the role of the TCA cycle as well as in the production of fatty acid.
Claisen may refer to: Rainer Ludwig Claisen, a German chemist Claisen rearrangement, a reaction of a allyl vinyl ether to a γ,δ-unsaturated carbonyl; Claisen condensation, a reaction between esters and carbonyl compounds in the presence of a strong base; Ireland–Claisen rearrangement, a chemical reaction of an allylic ester with strong base
n/a n/a Ensembl n/a n/a UniProt n a n/a RefSeq (mRNA) n/a n/a RefSeq (protein) n/a n/a Location (UCSC) n/a n/a PubMed search n/a n/a Wikidata View/Edit Human Fatty acid synthase (FAS) is an enzyme that in humans is encoded by the FASN gene. Fatty acid synthase is a multi-enzyme protein that catalyzes fatty acid synthesis. It is not a single enzyme but a whole enzymatic system composed of two ...