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Eighty per cent of the mined phosphorus is used to make fertilizers. Phosphates from fertilizers, sewage and detergents can cause pollution in lakes and streams. Over-enrichment of phosphate in both fresh and inshore marine waters can lead to massive algae blooms which, when they die and decay leads to eutrophication of freshwaters only. Recent ...
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
The decreasing saturation of seawater with respect to calcium carbonate, associated with ocean acidification, a result of increased carbon dioxide (CO 2) absorption by the oceans, poses a significant threat to marine calcifiers. As CO 2 concentrations in seawater rise, a decrease in pH and a reduction in carbonate ion concentrations in seawater ...
The phosphorus cycle is the biogeochemical cycle that involves the movement of phosphorus through the lithosphere, hydrosphere, and biosphere.Unlike many other biogeochemical cycles, the atmosphere does not play a significant role in the movement of phosphorus, because phosphorus and phosphorus-based materials do not enter the gaseous phase readily, [1] as the main source of gaseous phosphorus ...
Relationship of phosphate to nitrate uptake for photosynthesis in various regions of the ocean. Note that nitrate is more often limiting than phosphate The Redfield ratio or Redfield stoichiometry is the consistent atomic ratio of carbon , nitrogen and phosphorus found in marine phytoplankton and throughout the deep oceans.
The balance of these carbonate species (which ultimately affects the solubility of carbon dioxide), is dependent on factors such as pH, as shown in a Bjerrum plot.In seawater this is regulated by the charge balance of a number of positive (e.g. Na +, K +, Mg 2+, Ca 2+) and negative (e.g. CO 3 2− itself, Cl −, SO 4 2−, Br −) ions.
A change in pH by 0.1 represents a 26% increase in hydrogen ion concentration in the world's oceans (the pH scale is logarithmic, so a change of one in pH units is equivalent to a tenfold change in hydrogen ion concentration). Sea-surface pH and carbonate saturation states vary depending on ocean depth and location.
Since deep water (that is, seawater in the ocean's interior) is formed under the same surface conditions that promote carbon dioxide solubility, it contains a higher concentration of dissolved inorganic carbon than might be expected from average surface concentrations.