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In physics, the phase problem is the problem of loss of information concerning the phase that can occur when making a physical measurement. The name comes from the field of X-ray crystallography, where the phase problem has to be solved for the determination of a structure from diffraction data. [1]
A geometrical arrangement used in deriving the Kirchhoff's diffraction formula. The area designated by A 1 is the aperture (opening), the areas marked by A 2 are opaque areas, and A 3 is the hemisphere as a part of the closed integral surface (consisted of the areas A 1, A 2, and A 3) for the Kirchhoff's integral theorem.
Diffraction is the same physical effect as interference, but interference is typically applied to superposition of a few waves and the term diffraction is used when many waves are superposed. [1]: 433 Italian scientist Francesco Maria Grimaldi coined the word diffraction and was the first to record accurate observations of the phenomenon in 1660.
In electron diffraction, a diffraction pattern is produced by the interaction of the electron beam and the crystal potential. The real space and reciprocal space information about a crystal structure can be related through the Fourier transform relationships shown below, where () is in real space and corresponds to the crystal potential, and () is its Fourier transform in reciprocal space.
Diffraction geometry, showing aperture (or diffracting object) plane and image plane, with coordinate system. If the aperture is in x ′ y ′ plane, with the origin in the aperture and is illuminated by a monochromatic wave, of wavelength λ, wavenumber k with complex amplitude A(x ′,y ′), and the diffracted wave is observed in the unprimed x,y-plane along the positive -axis, where l,m ...
Because diffraction is the result of addition of all waves (of given wavelength) along all unobstructed paths, the usual procedure is to consider the contribution of an infinitesimally small neighborhood around a certain path (this contribution is usually called a wavelet) and then integrate over all paths (= add all wavelets) from the source to the detector (or given point on a screen).
Molecular replacement (MR) [1] is a method of solving the phase problem in X-ray crystallography.MR relies upon the existence of a previously solved protein structure which is similar to our unknown structure from which the diffraction data is derived.
Some of the earliest work on what would become known as Fresnel diffraction was carried out by Francesco Maria Grimaldi in Italy in the 17th century. In his monograph entitled "Light", [3] Richard C. MacLaurin explains Fresnel diffraction by asking what happens when light propagates, and how that process is affected when a barrier with a slit or hole in it is interposed in the beam produced by ...
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