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where is the mass of adsorbate adsorbed, is the mass of the adsorbent, is the pressure of adsorbate (this can be changed to concentration if investigating solution rather than gas), and and are empirical constants for each adsorbent–adsorbate pair at a given temperature.
Adsorption is the process by which a gas (or solution) phase molecule (the adsorbate) binds to solid (or liquid) surface atoms (the adsorbent). The reverse of adsorption is desorption, the adsorbate splitting from adsorbent. In a reaction facilitated by heterogeneous catalysis, the catalyst is the adsorbent and the reactants are the adsorbate.
The Langmuir equation states that for the adsorption of a molecule of adsorbate A onto a surface binding site S, a single binding site is used, and each free binding site is equally likely to accept a molecule of adsorbate: [1] + where: A is the adsorbate S is the surface binding site
For example, the surface charge of adsorbent is described by the ion that lies on the surface of the particle (adsorbent) structure like image. At a lower pH, hydrogen ions (protons, H +) would be more adsorbed than other cations (adsorbate) so that the other cations would be less adsorbed than in the case of the negatively charged particle. On ...
The adsorbent, as indicated in the figure, is assumed to be an ideal solid surface composed of a series of distinct sites capable of binding the adsorbate. The adsorbate binding is treated as a chemical reaction between the adsorbate gaseous molecule A g {\displaystyle A_{\text{g}}} and an empty sorption site S .
In physisorption, perturbation of the electronic states of adsorbent and adsorbate is minimal. The adsorption forces include London Forces, dipole-dipole attractions, dipole-induced attraction and "hydrogen bonding." For chemisorption, changes in the electronic states may be detectable by suitable physical means, in other words, chemical bonding.
Chemisorption is a kind of adsorption which involves a chemical reaction between the surface and the adsorbate. New chemical bonds are generated at the adsorbent surface. Examples include macroscopic phenomena that can be very obvious, like corrosion [clarification needed], and subtler effects associated with heterogeneous catalysis, where the catalyst and reactants are in different pha
Though bioaccumulation and biosorption are used synonymously, they are very different in how they sequester contaminants: . Biosorption is a metabolically passive process, meaning it does not require energy, and the amount of contaminants a sorbent can remove is dependent on kinetic equilibrium and the composition of the sorbents cellular surface. [9]