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For example, reaction of aniline with sulfuric acid at 180 °C produces sulfanilic acid, H 2 NC 6 H 4 SO 3 H. If bromine water is added to aniline, the bromine water is decolourised and a white precipitate of 2,4,6-tribromoaniline is formed. To generate the mono-substituted product, a protection with acetyl chloride is required:
The reaction of anthracene with N-methylformanilide, also using phosphorus oxychloride, gives 9-anthracenecarboxaldehyde: N -Methylformanilide and anthracene and phosphorus oxychloride In general, the electron-rich arene ( 3 ) must be much more active than benzene for the reaction to proceed; phenols or anilines are good substrates.
Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
Pellets of soda lye (sodium hydroxide) Pellets of potash lye (potassium hydroxide)Lye is a hydroxide, either sodium hydroxide or potassium hydroxide.The word lye most accurately refers to sodium hydroxide (NaOH), [citation needed] but historically has been conflated to include other alkali materials, most notably potassium hydroxide (KOH).
The hydrochloric acid and sodium hydroxide byproducts undergo a secondary reaction to release the byproducts of water and sodium chloride. The overall reaction is thus NaOCl + 2NH 3 → N 2 H 4 + NaCl + H 2 O. Excess ammonia and sodium chloride are removed by distillation, followed by azeotropic distillation with aniline to remove water.
The ester group is hydrolysed by sodium hydroxide to the carboxylic acid and decarboxylation again by application of heat to 4-hydroxyquinoline. Gould–Jacobs reaction. Extension of the Gould-Jacobs approach can prepare unsubstituted parent heterocycles with fused pyridine ring of Skraup type (see Skraup reaction). [1] Further reading: [4] [5] [6]
The reaction mechanism is not exactly known; two proposals are presented here. One possibility is at first an aldol condensation, starting from the enol form of the pyruvic acid (1) and the aldehyde, forming an β,γ-unsaturated α-ketocarboxylic acid (2). This is followed by a Michael addition with aniline to form an aniline derivative (3).
The first solvation shell of a sodium ion dissolved in water. An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl ...