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Mulliken charges arise from the Mulliken population analysis [1] [2] and provide a means of estimating partial atomic charges from calculations carried out by the methods of computational chemistry, particularly those based on the linear combination of atomic orbitals molecular orbital method, and are routinely used as variables in linear regression (QSAR [3]) procedures. [4]
Specific activity (symbol a) is the activity per unit mass of a radionuclide and is a physical property of that radionuclide. [ 1 ] [ 2 ] It is usually given in units of becquerel per kilogram (Bq/kg), but another commonly used unit of specific activity is the curie per gram (Ci/g).
Continuous charge distribution. The volume charge density ρ is the amount of charge per unit volume (cube), surface charge density σ is amount per unit surface area (circle) with outward unit normal nĚ‚, d is the dipole moment between two point charges, the volume density of these is the polarization density P.
Charge transfer coefficient, and symmetry factor (symbols α and β, respectively) are two related parameters used in description of the kinetics of electrochemical reactions. They appear in the Butler–Volmer equation and related expressions.
The formula provides a natural generalization of the Coulomb's law for cases where the source charge is moving: = [′ ′ + ′ (′ ′) + ′] = ′ Here, and are the electric and magnetic fields respectively, is the electric charge, is the vacuum permittivity (electric field constant) and is the speed of light.
When charged particles move in electric and magnetic fields the following two laws apply: Lorentz force law: = (+),; Newton's second law of motion: = =; where F is the force applied to the ion, m is the mass of the particle, a is the acceleration, Q is the electric charge, E is the electric field, and v × B is the cross product of the ion's velocity and the magnetic flux density.
The analysis of results is performed by determining the ratio of elements from within the sample and working out a chemical formula that fits with those results. This process is useful as it helps determine if a sample sent is the desired compound and confirms the purity of a compound.
Coulometry is the measure of charge, thus named after its unit the coulomb. Michael Faraday, known for his work in electricity and magnetism, made critical contributions to the field of electrochemistry. He discovered the laws of electrolysis, and in his recognition is the eponym of the Faraday constant.