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The vanadyl or oxovanadium(IV) cation, VO 2+, [1] is a functional group that is common in the coordination chemistry of vanadium. Complexes containing this functional group are characteristically blue and paramagnetic. A triple bond is proposed to exist between the V 4+ and O 2− centers. [2]
A carbon–oxygen bond is a polar covalent bond between atoms of carbon and oxygen. [ 1 ] [ 2 ] [ 3 ] : 16–22 Carbon–oxygen bonds are found in many inorganic compounds such as carbon oxides and oxohalides , carbonates and metal carbonyls , [ 4 ] and in organic compounds such as alcohols , ethers , and carbonyl compounds .
Cp 2 V 2 (CO) 5 featuring a pair of semi-bridging CO ligands. [15] Organovanadium chemistry is the chemistry of organometallic compounds containing a carbon (C) to vanadium (V) chemical bond. [16] Organovanadium compounds find only minor use as reagents in organic synthesis but are significant for polymer chemistry as catalysts. [17]
In the dioxygen molecule O 2, each oxygen atom has 2 valence bonds and so is divalent (valence 2), but has oxidation state 0. In acetylene H−C≡C−H, each carbon atom has 4 valence bonds (1 single bond with hydrogen atom and a triple bond with the other carbon atom). Each carbon atom is tetravalent (valence 4), but has oxidation state −1.
The oxidation state of oxygen is −2 in almost all known compounds of oxygen. The oxidation state −1 is found in a few compounds such as peroxides . [ 125 ] Compounds containing oxygen in other oxidation states are very uncommon: −1/2 ( superoxides ), −1/3 ( ozonides ), 0 ( elemental , hypofluorous acid ), +1/2 ( dioxygenyl ), +1 ...
The oxidation state of oxygen is −2 in almost all known compounds of oxygen. The oxidation state −1 is found in a few compounds such as peroxides . Compounds containing oxygen in other oxidation states are very uncommon: − 1 ⁄ 2 ( superoxides ), − 1 ⁄ 3 ( ozonides ), 0 (elemental, hypofluorous acid ), + 1 ⁄ 2 ( dioxygenyl ), +1 ...
V 2 O 5 + SO 2 → 2 VO 2 + SO 3. The catalyst is regenerated by oxidation with air: 4 VO 2 + O 2 → 2 V 2 O 5. Similar oxidations are used in the production of maleic anhydride: C 4 H 10 + 3.5 O 2 → C 4 H 2 O 3 + 4 H 2 O. Phthalic anhydride and several other bulk organic compounds are produced similarly.
2. The diatomic superoxide ion O − 2 has an overall charge of −1, so each of its two equivalent oxygen atoms is assigned an oxidation state of − 1 / 2 . This ion can be described as a resonance hybrid of two Lewis structures, where each oxygen has an oxidation state of 0 in one structure and −1 in the other. For the ...