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The Buchner ring expansion is a two-step organic C-C bond forming reaction used to access 7-membered rings. The first step involves formation of a carbene from ethyl diazoacetate , which cyclopropanates an aromatic ring.
It is commonly thought to be named after the Nobel Laureate Eduard Buchner (without umlaut), but it is actually named after the industrial chemist Ernst Büchner. [2] A Büchner funnel fitted with Sintered Disc made of Boro 3.3 Glass. Diagram of filtration set-up using a Büchner flask
Tukey defined data analysis in 1961 as: "Procedures for analyzing data, techniques for interpreting the results of such procedures, ways of planning the gathering of data to make its analysis easier, more precise or more accurate, and all the machinery and results of (mathematical) statistics which apply to analyzing data." [3]
Buchner funnels are made of porcelain and include a plate of sintered glass or perforated porcelain. These are used in filtration under low pressure with a Buchner flask. [2] Hot filtration funnel is a less commonly seen funnel where the funnel is jacketed, and surrounded by a heated fluid. [3]
A symmetric inverted funnel shape arises from a ‘well-behaved’ data set, in which publication bias is unlikely. An asymmetric funnel indicates a relationship between treatment effect estimate and study precision.
Eduard Buchner (German: [ˈeːduaʁt ˈbuːxnɐ] ⓘ; 20 May 1860 – 13 August 1917) was a German chemist and zymologist, awarded the 1907 Nobel Prize in Chemistry for his work on fermentation. [ 1 ]
His father was the pharmacist, chemist, industrialist and politician Wilhelm Büchner.Ernst was also the nephew of the playwright Georg Büchner and the philosopher, physiologist and physician Ludwig Büchner.
A funnel (E) contains a sample of soil or leaf litter (D), and a heat source (F), in this case an electric lamp (G), heats the sample. Animals escaping from the desiccation of the sample descend through a filter (C) into a preservative liquid (A) in a receptacle (B).