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The chloroform molecule can be viewed as a methane molecule with three hydrogen atoms replaced with three chlorine atoms, leaving a single hydrogen atom. The name "chloroform" is a portmanteau of terchloride (tertiary chloride, a trichloride) and formyle, an obsolete name for the methylylidene radical (CH) derived from formic acid. [citation ...
In 1835, the French chemist Auguste Laurent recognised chloroform as CCl 2 • HCl (then written as C 8 Cl 8 • H 4 Cl 4) [a] in his paper on analysing some organohalides. Laurent also predicted a compound seemingly consisting of 2 parts dichlorocarbene which he named Chlorétherose (possibly Tetrachloroethylene, which was not known to exist at the time.) [8]
Table data obtained from CRC Handbook of Chemistry and Physics 44th ed. log 10 of Chloroform vapor pressure. Uses formula: ...
In the laboratory, sodium formate can be prepared by neutralizing formic acid with sodium carbonate. It can also be obtained by reacting chloroform with an alcoholic solution of sodium hydroxide. CHCl 3 + 4 NaOH → HCOONa + 3 NaCl + 2 H 2 O. or by reacting sodium hydroxide with chloral hydrate. C 2 HCl 3 (OH) 2 + NaOH → CHCl 3 + HCOONa + H 2 O
According to some evidence, the discovery of chloroform can be traced back to the year 1831. In a letter to Professor Silliman dated February 15, 1832. Mr. Guthrie claims that the substance obtained by washing it with a strong solution of potassium carbonate was considered as "distilled off sulphuric acid."
When the alkyl radical is fully formed in the transition state, it can benefit fully from any resonance stabilization present thereby maximizing selectivity. [dubious – discuss] [citation needed] Bond dissociation energies strongly influence any radical process and in a few unusual cases, free-radical halogenation can regioselect.
The resulting HCl can be reused in oxychlorination reaction. Thermally induced dehydrofluorinations are employed in the production of fluoroolefins and hydrofluoroolefins. One example is the preparation of 1,2,3,3,3-pentafluoropropene from 1,1,2,3,3,3-hexafluoropropane: CF 2 HCH(F)CF 3 → CHF=C(F)CF 3 + HF
Different lipids can be bought either dissolved in chloroform or as lyophilized lipids. In the case of lyophilized lipids, they can be solubilized in chloroform. Lipids are then mixed with a desired molar ratio. Then chloroform is evaporated using a gentle stream of nitrogen (to avoid oxygen contact and oxidation of lipids) at room temperature.